储氢材料10-Hydrogen Storage materials.PPTVIP

Ⅳ. Preparation equipments and techniques for HSAs 2) replacement and diffusion (置换扩散法) MgCu2, Mg2Ni Theories: Mg (powder) + organic (liquid) + Cu salt (CuBr2) organic solvent: benzene (苯) or acetonitrile (CH3CN, 氰化甲烷) → Cu deposited on Mg → heat up to higher temperature for diffusion of Cu in Mg Ⅳ. Preparation equipments and techniques for HSAs For example: CuBr2 (20g) + Mg (30g) + CH3CN Advantages: porous full of cracks cleavage defects; －much more active. much higher specific surface. this alloy － 11.65 m2/g; melting alloy － 0.65 m2/g. → Mg + Cu coexisting → thermo diffusion under Ar and 550~600℃ → Mg2Cu Ⅳ. Preparation equipments and techniques for HSAs 3) hydriding combustion synthesis (氢化燃烧合成法) the well mixed powder was compressed ; Mg2Ni ( or Mg + x% Ni) heat up to 800~900 ℃ under a H2 atmosphere; then cool down to room temperature; obtain Mg2NiH4. Ⅳ. Preparation equipments and techniques for HSAs 4) mechanical alloying planetary ball mill － a small quantity 50 g； 5) fast solidification (1) melt spinning stirring ball mill － a mass of 10 ~ 500 g. (2) atomizing (3) splat cooling Milling under an inert atmosphere or in a liquid. Ⅳ. Preparation equipments and techniques for HSAs melt spinning atomizing Tel: 0571- 8795 1152 Email: lxchen@zju.edu.cn Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Preparation and Characterization of Hydrogen Storage Alloys and Their Hydrides Lecture I X 1.1 Importance 1) Preparation For research － well defined homogeneous with low impurities . I . Introduction 2) Characterization For research － guarantee accurate intrinsic properties; For industrial scale production － good quality HSAs and hydrides; －cheap . 1.2 Contents Preparatory academic work (phase diagrams); I . Introduction Laboratory scale preparation; Industrial scale preparation; Characterization of HSAs; Charac