耐候钢干湿交替环境下模拟大气腐蚀行为的研究.pdfVIP

耐候钢干湿交替环境下模拟大气腐蚀行为的研究 吴红艳 杜林秀 刘相华1 （轧制技术及连轧自动化国家重点实验室，东北大学，沈阳 110819 ） 摘 要 在模拟工业大气环境下，利用干湿交替加速腐蚀方法和电化学实验方法研究了实验钢的耐腐蚀行为。结果 表明，Mn-Cu 耐候钢的腐蚀速度与SPA-H 钢相当但低于16Mn 钢。在实验初期腐蚀速度随循环次数的增加而增大， 细晶粒耐候钢比粗晶粒腐蚀速度快；在后期随循环次数的增加而减小，粗细晶粒耐候钢腐蚀速度一致。Mn-Cu 耐候 钢锈内锈层致密，由α-FeOOH 和少量γ-Fe O 组成。16Mn 钢锈层由α-FeOOH、γ-Fe O 和Fe O 组成。电化学实 2 3 2 3 3 4 验表明，腐蚀产物促进阴极过程，抑制阳极过程。细晶粒有利于保护性内锈层的快速形成，其电极化曲线的自腐蚀 电位和自腐蚀电流变化较大。 关键词 耐候钢 干湿交替 大气腐蚀 锈层结构 电极化曲线 Study on Corrosion Behavior of Weathering Steel under Wet/Dry Cycles of Simulation a Atmosphere Environment Wu Hongyan Du Linxiu Liu Xianghua (State Key Lab of Rolling and Automation, Northeastern University, Shenyang, 110819) Abstract It showed that corrosion rate of weathering steel was near to SPA-H steel and lower than that of 16Mn steel. The corrosion rate increased with increasing the wet / dry cycles in the initial stage of the test, and corrosion rate of fine grained weathering steel was faster than that of coarse grain. However it decreased with increasing the wet / dry cycles in the latter stage of the test, and corrosion rate of all Mn-Cu weathering steel was the same in the latter. Inner rust layer of weathering steel was dense and mainly composed of α-FeOOH and a little of γ-Fe2O3 composition. Rust layer of 16Mn steel was composed of α-FeOOH, γ-Fe O and Fe O composition. The polarization behavior of the rusted steel indicated that the 2 3 3 4 corrosion product promoted the cathodic process while restrained the anodic process. Fine grain was in favor of the rapid formation of protective rust layer, and the change of corrosion potential and corrosion current of fine grain weathering