LDPE聚合过程设计及模拟.pdf

LDPE 聚合过程设计及模拟 摘 要 低密度聚乙烯(LDPE)又称高压聚乙烯是世界上产量和需求量最大的一类产品， 由于物化性能优异，成型加工简单，价格相对便宜，应用范围已深入到国民经济各 个部门。 本文介绍了聚乙烯的现状、生产工艺及LDPE 装置和国内外研究状况、应用领 域和应用现状、生产概况、市场需求和应用前景以及工艺流程和控制。进行了聚合 全系统的物料进行衡算；聚合釜选型和工艺尺寸计算；搅拌设备的选型和功率计算 以及对聚合反应器首釜进行热量衡算。并依此绘制工艺流程图和聚合釜工艺装配 图。 而设计的主要工具就是目前最为流行的化工过程模拟软件ASPEN PLUS ， 通过模拟低密度聚乙烯的聚合过程，运用ASPEN 中Polymer 模块中的灵敏度分析， 对分子量影响因素进行了探索分析。 关键词：聚乙烯，LDPE ，ASPEN ，流程模拟，灵敏度分析 I LDPE 聚合过程设计及模拟 Abstract Low-density polyethylene (LDPE),also called polyethylene by high pressure process, is one of products of the highest demand and the biggest output in the world .Because the polyethylene has the excellent function of , simple process of model,cheapness in price, so the polyethylene’s application has gone deeply into every section of country. The main of present design introduced the current status of polyethylene .At the same time , the characteristic of products, processes and the equipment of LDPE.etc is mentioned. The status of research on LDPE in domesticity and abroad, the situation of production, the need of market and applying in the future were also introduced. The total material balance of polymerization system; the selection and design of polymerization reactor; and the selection of stirring devices and the calculation of power thereof, and the heat balance of the first polymerization reactor were finished. And the technical flow chart and the polymerization kettle technical assemble chart is pictured. And the tool which I used in the design is one of the most popular chemical technology simulation software in the world— ASPEN PLUS .It was used to simulate the ethyl