Sc2Mo3O12_ZrO2可控热膨胀复合材料的制备.docVIP

  Sc2Mo3O12/ZrO2 可控热膨胀复合材料的 制备# 程晓农，朱君君，杨娟* 5 10 （江苏大学材料科学与工程学院，江苏 镇江 212013） 摘要：采用固相法成功制备了纯度较高的各向异性负热膨胀材料 Sc2Mo3O12。将 ZrO2 与 Sc2Mo3O12 按一定比例混合，在 1000烧结 10h 制备 Sc2Mo3O12/ZrO2 复合材料。通过 X 射线衍 射(XRD)仪、扫描电子显微镜(SEM)、能谱仪(EDS)和热膨胀仪对合成样品的晶体结构、断面 形貌和热膨胀性能进行表征。结果表明：样品组元为正交相 Sc2Mo3O12 和单斜相 ZrO2；在 30~600 内，Sc2Mo3O12/ZrO2 复合材料的热膨胀系数皆线性一致，并且通过改变 Sc2Mo3O12 的体积分数， 其热膨胀系数可以控制为正、负或零。其中 50vol%Sc2Mo3O12/ZrO2 复合材料在 30~600的平 -6 -1 关键词：固相法；Sc2Mo3O12；ZrO2；复合材料；可控热膨胀；负热膨胀 中图分类号：TB332 15 Preparation of Sc2Mo3O12/ZrO2 composites with controllable thermal expansion CHENG Xiaonong, ZHU Junjun, YANG Juan (School of Materials Science and Engineering, Jiangsu University, JiangSu ZhenJiang 212013) 20 25 30 35 40 Abstract: Sc2Mo3O12 which exhibits excellent anisotropic negative thermal expansion was synthesized using solid-state reaction. Sc2Mo3O12/ZrO2 composites were prepared by mixing ZrO2 and Sc2Mo3O12 at different volume ratios and sintered at 1000℃ for 10 h. The crystal structure, fracture surface morphology and thermal expansion properties of the synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and dilatometer. The results indicate that the obtained samples contain only orthorhombic Sc2Mo3O12 and monoclinic ZrO2 phase without other phases. All the thermal expansion properties of Sc2Mo3O12/ZrO2 composites are linear in 30-600 ℃ and their thermal expansion coefficients can be controlled as positive, negative or even zero by adjusting the volume fraction of Sc2Mo3O12. 50vol%Sc2Mo3O12/ZrO2 composite shows almost zero thermal expansion, and its average thermal expansion coefficient is -0.13×10-6 ℃-1 in 30-600 ℃. Keywords: solid-state reaction; Sc2Mo3O12; ZrO2; composites; controllable thermal expansion; negative thermal expansion 0 引言 热膨胀对机械、电子、光学的器件材料至关重要，许多器件往往因为环境温度的改变引 起形状和尺寸改变，致使器件的性能失效，为了提高材料的抗热冲击性能、延长材料的使用 寿命，低膨胀或零膨胀材料的开发研究就显得尤为重要。近年来负热膨胀(negative thermal expansion，NTE)材料的发现为解决这类问题提供了可能，有望通过将具有