臭氧氧化去除水中残杀威效果与机理.docVIP

  臭氧氧化去除水中残杀威效果与机理# 沈吉敏，高国瀛，陈忠林，何雷* （哈尔滨工业大学市政环境工程学院城市水资源与水环境国家重点实验室,哈尔滨，150090） 5 10 15 20 25 30 摘要：利用高锰酸钾、氯、臭氧以及粉末活性炭对对极性非常大消杀剂残杀威的去除能力进 行了考察，发现除了臭氧以外，其它几种方法都不能很好的去除水中的残杀威。对臭氧氧化 降解水中的残杀威的影响因素、动力学和机理进行了研究，发现 pH、碳酸盐、羟基自由基 抑制叔丁醇对臭氧氧化残杀威的过程影响显著，说明臭氧氧化去除残杀威受羟基自由基控 制，动力学研究表明臭氧分子与残杀威的直接反应速率常数 kd 为 38. L/(mol· s)；臭氧氧化 去除水中残杀威的表观速率 Kabs 随着 pH 的升高，室温条件下 pH 为 6.45、7.06、7.43 和 7.80 对应的 Kabs 分别为 125、199、241 和 533 L/(mol· s)，残杀威臭氧化过程中可能生成可能生 成羟基残杀威或脱甲基生成 2-异丙氧基苯基氨基甲酸酯。 关键词：臭氧化；残杀威；动力学；降解机理 中图分类号：x703.1 Ozonation Degradation of propxour in Aqueous Solution SHEN Jimin, GAO Guoying, CHEN Zhonglin, HE Lei (State Key Laboratory of Urban Water Resource and Environment, School of Municipal Environmental Engineering, Harbin Institute of Technology, Harbin, 150090, Heilongjiang, China) Abstract: The present study investigates the degradation of very large polar propoxur with potassium permanganate, chlorine, ozone and powdered activated carbon. The experimental results indicate that only ozone have a good removal efficiency on propoxur. The factors, kinetics and mechanism have been studied during the ozonation of propoxur. The results were showed that pH, carbonate and the radical inhibitor tertiary butyl alcohol affect the ozonation process of propoxur significantly, indicating the ozonation of propoxur is controlled by the radical inhibitor tertiary butyl alcohol. Kinetic studies have shown that the rate constant of the reaction of ozone with propoxur was found to be 38 L/(mol.s), the corresponding apparent rate constants was increases as pH increase. On the room temperature, the corresponding apparent rate constants for pH 6.45,7.06,7.43 and 7.80 are 125, 199, 241 and 533 L/(mol.s) respectively. The main degradation products identified were hydroxy propoxur or demethylation generation 2-isopropoxy-phenyl carbamate. Key words: Ozonation; Propxour; Kinetics; Mechanism of degradation 35 0 引言 残杀威（Propoxur；o-isopropoxyphenyl methylcarbamate，简称 PHC）是一种氨基甲酸 酯杀虫剂，是世界卫生组织（WHO）推荐的四种卫生用药