毕业论文--碱铝硼硅系玻璃结合剂的性能.docVIP

摘 要 本课题主要是研究碱（Na2O+K2O）铝硼硅系玻璃结合剂的几种重要的性能，以及不同含量的B2O3对结合剂性能的影响。 通过膨胀仪对结合剂的烧结点、烧结范围，热膨胀系数进行测定；通过差热分析仪对液相产生温度、核化温度、晶化温度进行测定，得出烧成制度；通过红外光谱仪进行对结合剂结构，得出不同成分对玻璃（结合剂）结构的影响。 研究结果表明：通过热膨胀分析得出随硼含量增加，热膨胀性呈现出先增大后减小的趋势，说明当硼含量增大到一定值时会出现硼反常现象；通过对玻璃料进行红外分析发现玻璃料中硼主要处于三次配位，且随硼含量的增加，三配位在增加，四配位的硼也可能增加。通过差热分析随硼含量的增加核化温度、晶化温度 关键词：B2O3 差热分析 红外分析 膨胀 烧结范围 Title Alkali aluminum borosilicate glass binder’s performance Abstract The main topic is the study of alkali (Na2O + K2O) aluminum borosilicate glass binder’s several important properties and the effect of different levels of B2O3 on binder performance. Sintering point of the binder, sintering range, the coefficient of thermal expansion were measured by the dilatometer .The liquid temperature, nuclear temperature, crystallization temperature were determined by differential thermal analyzer to come to the firing system. By infrared spectroscopy for the analysis of the structure of the binder. Come to the effect of different components on glass structure (binding agent). The results show that :By thermal expansion analysis obtained with the boron content increases, the thermal expansion showed a decreasing trend in the first increase and then note boron anomaly will appear when the boron content increases to a certain value. Found by infrared analysis of the glass frit frit-B is three times with the form. And with increasing boron content, three with increasing tetrahedral coordination of boron may also increase.Nucleation temperature and the crystallization temperature with the increase of boron content analysis can be drawn by differential thermal. Keywords: B2O3, Differential thermal analysis , Infrared Analysis , Thermal expansion, Sintering range  目录 Abstract II 1 引言 IV 2 结合剂原料的选定及配方的计算 V 2.1原料的选定 V 2.2结合剂的配方 VI 2．2．1配方中各组成的性质特点 VI 2．2．2具体配方制定 VII 2.3 实验仪器及设备 VII 3 粉体玻璃料的制备以及块状试样的压制 VII 3.1粉体玻璃料的制备 VII 3.2块状试样的压制 IX 4 实验及分析 IX 4．1烧结范围的确定 IX 4.1.1烧结范围的理论知识 IX 4.1.2烧结范围实验及结果分析 IX 4.2差热分析 XII 4.2.1差热分析原