负载型零价铁的制备及对偶氮染料金黄2GL的脱色性能研究环境工程毕业论文.doc

毕业论文（设计） 题　　目：负载型零价铁的制备及对偶氮染料金黄2GL的脱色性能研究  摘要:本研究合成了负载在阳离子交换树脂表面的纳米零价铁(NZVI)，并研究了该材料分散于水溶液中时，对水溶性偶氮染料的降解效果，考察了pH值、温度、铁的添加量对脱色性能的影响。实验表明：该材料对0.05 g·L?1偶氮染料金黄2GL的降解能效果良好，pH值是影响降解效率的关键因素；在pH为5，温度为30℃，ZVI添加量为60g/L时，脱色效率最高，18min后的降解效率达到85%。 关键词:偶氮染料；阳离子交换树脂；零价铁；脱色  Abstract: In this study, the nanoscale zero valent iron on surface of the cation exchange resin was synthetized, and the degradation efficiency of water-soluble azo dyes was researched when the material is dispersed in aqueous solution and effects of pH, temperature and the addition of ZVI was studied. The result of experiment showed that the degradation efficiency of azo dyes on the concentration of 0.05g/L is favorable. After 18 min, the degradation efficiency could be 85% or more. It was found that pH is the key factor of degradation effects. In the condition that pH is 5, temperature is 30℃, and the amount of iron addition is 60g/L, the decolorization efficiency Keywords: azo dyes; cation exchanger resin; zero valent iron; decolorization 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc325485793 1 绪论 PAGEREF _Toc325485793 \h 1 HYPERLINK \l _Toc325485794 1.1 偶氮染料的来源 PAGEREF _Toc325485794 \h 1 HYPERLINK \l _Toc325485795 1.2 偶氮染料的危害 PAGEREF _Toc325485795 \h 1 HYPERLINK \l _Toc325485796 1.3 偶氮染料的降解方法 PAGEREF _Toc325485796 \h 1 HYPERLINK \l _Toc325485797 1.4 零价铁的应用 PAGEREF _Toc325485797 \h 2 HYPERLINK \l _Toc325485798 2 材料和方法 PAGEREF _Toc325485798 \h 4 HYPERLINK \l _Toc325485799 2.1 实验内容 PAGEREF _Toc325485799 \h 4 HYPERLINK \l _Toc325485800 2.1.1 负载型零价铁的制备 PAGEREF _Toc325485800 \h 4 HYPERLINK \l _Toc325485801 2.1.2 零价铁降解偶氮染料金黄2GL PAGEREF _Toc325485801 \h 4 HYPERLINK \l _Toc325485802 2.2 分析方法 PAGEREF _Toc325485802 \h 5 HYPERLINK \l _Toc325485803 2.2.1 COD的测定 PAGEREF _Toc325485803 \h 5 HYPERLINK \l _Toc325485804 2.2.2 色度去除率的测定 PAGEREF _Toc325485804 \h 5 HYPERLINK \l _Toc325485805 2.3 仪器和试剂 PAGEREF _Toc325485805 \h 6 HYPERLINK \l _Toc325485806 2.3.1 仪器 PAGEREF _Toc32