毕业论文--复合催化剂K3PW12O40TiO2的制备表征及光催化性能分析研究.doc

PAGE 本科毕业论文（设计） 题　　目： 复合催化剂K3PW12O40/TiO2的制备、 表征及光催化性能研究　 　 复合催化剂K3PW12O40/TiO2的制备、表征及光催化性能研究 摘 要 采用溶胶-凝胶法制备了K3PW12O40/TiO2复合催化剂，并用红外光谱、紫外-可见光谱、X射线衍射和扫描电镜等方法对所制备的催化剂进行了表征,结果表明催化剂中的二氧化钛为锐钛矿型,磷钨酸钾仍保持其Keggin结构的基本骨架,磷钨酸钾与二氧化钛之间存在着很强的相互作用。在紫外光照射下，以有机污染物罗丹明6G光催化降解目标，考察了催化剂的光催化活性。研究结果表明，K3PW12O40/TiO2复合物具有一定的催化效果。 关键词：K3PW12O40/TiO2;光催化;罗丹明6G Preparation, Characterization, and Photocatalytic Performance of KPW12O40/TiO2 Composite Catalyst Abstract Used the sol-gelatin legal system to prepare the K3PW12O40/TiO2 compound catalyst, and with methods and so on infrared spectrum, ultraviolet-obvious spectrum, X-ray diffraction and scanning electron microscope to the catalyst which prepared has carried on the attribute, finally indicated that in the catalyst the titanium dioxide for the anatase, the phospho-wolframic acid potassium still maintained its Keggin structure the basic skeleton, between the phospho-wolframic acid potassium and the titanium dioxide has the very strong interaction. Under ultraviolet ray illumination, by organic pollutant Rodin bright 6G photochemical catalysis degeneration goal, inspected the catalyst photochemical catalysis activeness. The findings indicated that the K3PW12O40/TiO2 compound has certain catalyzed effect. Keywords: K3PW12O40/TiO2；Photocatalysis；Rhodamine 6 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc169098822 第一章 前 言 PAGEREF _Toc169098822 \h 1 HYPERLINK \l _Toc169098823 1.1 TiO2的光降解作用及改性方法简介 PAGEREF _Toc169098823 \h 1 HYPERLINK \l _Toc169098824 1.2杂多酸盐性能简介 4 HYPERLINK \l _Toc169098830 1.3 TiO2复合杂多酸盐的研究现状 4 HYPERLINK \l _Toc169098832 1.4 本文研究方法与对象 5 HYPERLINK \l _Toc169098832 1.5实验技术路线 5 HYPERLINK \l _Toc169098833 第二章 实验部分 6 HYPERLINK \l _Toc169098834 2.1 实验药品及仪器 6 HYPERLINK \l _Toc169098835 2.1.1实验药品 6 HYPERLINK \l _Toc169098836 2.1.2实验仪器 6 HYPERLINK \l _Toc169098837 2.2 实验步骤 6 HYPERLINK \l _Toc169098839 2.2.1 TiO2与磷钨酸盐光催化剂的制备 6 HYPERLINK \l _Toc169098840 2.2.2光催化剂的FT-IR和XRD测试 6 HYPERLINK \l _T