毕业论文-氧化物超双疏微结构的制备及其润湿性特征的研究-Zn基.doc

摘 要 润湿性是固体表面的重要特征之一，人工控制和制备固体表面的润湿性已成为研究的热点，而且逐渐被应用于国防、工农业生产和人们日常生活等不同领域。表面的疏水性能通过常用的表面与水的接触角大于150o，而滚动角小于10o来表示。 润湿性由表面化学组成和微观几何结构共同决定。所以寻求和制备低表面自由能的材料是制备超疏水表面的前提条件。本文将采用饱含—的全氟羧酸来降低表面自由能。我们利用常用工程金属（锌，铝，铁，镍等）及其合金（Zn-Fe合金和黄铜）通过在全氟酸溶液中的电化学反应成功的制备出防水和油良好的超双疏表面，通过在控制链长，全氟酸浓度，处理时间，纹理粗糙的结构不同基底上得以实现。处理表面的结果显示超双疏结构是由于其特殊的表面成分和微观结构的影响。 关键字：超双疏；疏水性；润湿性；接触角 Abstract Solid surface wettability is one of the important characteristics. Artificial control and the preparation of solid surface wettability has become the focus of research, and gradually is applied in the defense, industry, agriculture and daily life and people in different fields. The surface of the surface of the water used performance by the contact Angle and the water more than 150 o, and rolling Angle is less than 10 o to said. By surface wettability chemical composition and micro geometry structure decided together. So for the preparation and low surface of the free energy material is the preparation of the water meter superhydrophobic prerequisite. This article will use the full of carboxylic acid-all the fluorine to reduce surface free energy. We use ordinary engineering metal (zinc, aluminum and iron, nickel, etc) and alloy (Zn-Fe alloy and brass) through the in all the fluorine acid solution of electrochemical reactions successful preparation waterproof and oil out of the good of the double surface, through in the control chain long, all the fluorine acid concentration, the processing time, rough texture of different structure base can be realized. The results showed that the surface treatment of the dual structure is due to its special surface composition and the micro structure of the influence. Key words: Superamphiphobic；Hydrophobic；wettability ； contact angle 目录 TOC \o 1-2 \h \z HYPERLINK \l _Toc327267510 摘 要 PAGEREF _Toc327267510 \h 6 HYPERLINK \l _Toc327267511 Abstract PAGEREF _Toc327267511 \h 7 HYPERLINK \l _Toc327267512 目录 PAGEREF _Toc327267512 \h 8 HYPERLINK \l _Toc327267513 第1章 论文综述 PA