Cr-Al-C系陶瓷体系设计及反就路径分析.doc

PAGE 毕业论文 题 目: Cr-Al-C系陶瓷体系设计及 反应路径研究 摘 要 本研究主要对利用铬粉、铝粉和石墨三种单质为原料，采用热压法制备Cr2AlC三元层状可加工陶瓷的体系和反应路径进行了研究，首先在氩气的保护下对原料进行了差热分析，并对在不同温度下烧结制备的材料进行了X－射线衍射分析，结合扫描电镜、能谱分析等先进仪器设备，研究了其物相组成和结构形貌。 对Cr2AlC陶瓷的反应路径进行分析表明：以铬粉、铝粉和石墨为原料且原子量比Cr：Al：C＝1：1.2：1在850－1250℃热压烧结，并利用X衍射仪、电子探针和能量分散光谱进行反应路径分析。差热分析和X衍射分析表明Cr2AlC的连续物相组成可在Cr－Al二元系统相图的基础上进行分析，并且发Cr9Al17、Cr5Al8和Cr2Al是在加热过程中产生的中间相化合物。Cr2AlC的含量随Cr-Al金属间化合物的反应温度的增加而增加，在1050℃时样品的中间相主要为Cr2Al金属间化合物，未参加反应的石墨在1250℃以上随中间相的消失而成为样品中的残余相，Cr2AlC成为主晶相，同时含有少量的Cr7C3相。 关键词： Cr2AlC陶瓷 可加工陶瓷 金属间化合物 扫描电镜（SEM） Title system designing and phase formation sequence of Cr-Al-C ceramics Abstract This study mainly to used the chromium powder, the aluminite powder and the graphite three kind of simple substances as raw material, system and the reaction way has been studied of Cr2AlC layered and possible processed ceramics,which prepared by hot- pressing process .First differential thermal analysis has been used under the argon protection to raw material.And X-ray diffraction(XRD) has been carried on the ceramics material which maked under the different temperature.At the same time, scanning electric microscope（SEM）and energy dispersive spectrum(EDX)were employed for identification of phase assembly and structure appearance. The reaction process of Cr2AlC ceramics was analyzed,in which the samples were prepared for composition Cr:Al:C=1:1.2:1 by hot-pressing in argon in the range of 850–1450℃ using Cr,Al and graphite powders as the starting materials.X-ray diffraction(XRD), scanning electric microscope (SEM)and energy dispersive spectrum(EDX)were employed for identification of phase assembly and analysis of reaction route of the samples.The phase formation sequence of Cr2AlC was finally analyzed based on phase diagram of the Cr–Al binary system combined with the results of differential thermal analysis(DTA)and X-ray diffraction(XRD