水平磁场对聚砜-Fe3O4超滤膜性能的影响论文定稿.doc

PAGE 毕 业 设 计（论 文） 题 目 水平磁场对聚砜-Fe3O4超滤 膜性能的影响 摘 要 本文阐述了超滤的原理、研究概况、制备材料和方法以及影响超滤膜性能的因素，同时介绍了超滤膜的应用及膜在应用过程中出现的主要问题与解决方法。 有文献报道了在有机膜中添加无机填料可以增强膜的机械强度，提高膜的渗透性、耐污染性。目前研究中所使用的无机填料主要有SiO2、Al2O3、ZrO2、TiO2等，以Fe3O4为填料的尚不多见；Fe3O4具有良好的亲水性和磁性，如果在制膜的过程中引入磁场作用将改变Fe3O4的排列状态，进而会影响膜的性能。 本实验尝试以聚砜为基材、聚乙烯吡咯烷酮为致孔剂、二甲基乙酰胺为溶剂，四氧化三铁为填料，采用浸没沉淀相转化法分别在水平磁场和无磁场的条件下制备聚砜- Fe3O4超滤膜，并采用死端超滤装置测试了的膜的渗透性，截留率，耐污染性等性能。 实验结果表明：超滤膜通量、截留率随Fe3O4含量增加而增加；Fe3O4含量高于40wt%时，未磁化膜性能有明显的提高，Fe3O4含量高于60wt%时，磁化膜性能有明显的提高；相同Fe3O4含量下，Fe3O4高于60wt%时，磁化膜通量更大，截留率略低，绝对耐污染性更强，相对耐污染性更弱。 关键词：超滤；有机-无机膜；聚砜；四氧化三铁 Abstract This paper introduces the UF principle, research survey ,materials preparation and the preparation methods and the influence factors for performance of UF membranes. Meanwhile ,it also introduced application and existing problems of UF and the solutions. Some research expose that adding inorganic in organic membranes can enhance the strength ,improve the permeability and the anti-fouling conditions of membrane .At present ,main inorganic-fillers are SiO2、Al2O3、ZrO2、TiO2 ect. ,it is seldom to see the research on the Fe3O4 as inorganic fillers ;Fe3O4 has great HYPERLINK /dict_result.aspx?searchword=%e4%ba%b2%e6%b0%b4%e6%80%a7tjType=sentencestyle=t=hydrophilicity hydrophilicity and magnetism. Introducing magnetic effect in the membrane preparation ,compare to the in-magnetic effect ,the form of Fe3O4 would be changed ,so that the performance of membrane can be influenced further. In this experiment ,PSF-Fe3O4 membrane was prepared by substrate material of PSF, the filler of Fe3O4, the solution of DMAC and the pore-foaming agent of PVP under magnetic field or nonmagnetic field through the method of immersion precipitation phase inversion . Cross-flow filtration equipment was used to measure the permeability ,the anti-fouling conditions and rejection rate of the membrane . It shows that the rejection rate and permeability of the membranes are improved with the increasing of the concentration of Fe3O4; and when