差分吸收光谱测量中LED 光源恒温控制的实现.docVIP

差分吸收光谱测量中LED光源恒温控制的实现* 凌六一1,2，谢品华1 ?，秦敏1，王界1，叶丛雷1，刘建国1，刘文清1 1.中国科学院安徽光学精密机械研究所，安徽合肥，230031 2.安徽理工大学电气与信息工程学院，安徽淮南，232001 ±0.1℃。在相同的测试条件下与无恒温相比，具有恒温功能的LED光源剩余噪声明显偏低，进一步验证了设计方案的可行性。 关键词：LED，DOAS，恒温控制，PID算法 Realization of Thermostatic Control of LED as Light Source for Differential Optical Absorption Spectroscopy Measurements Liuyi Ling1,2，Pinhua Xie1 ?，Min Qin1，Jie Wang1，Conglei Ye1，Jianguo Liu1，Wenqing Liu1 1.Anhui Institute of Optics and Fine Mechanics,Chinese Academy of Science, National Engineering Research Center for Environmental Optical Monitoring Instrument, Hefei,China,230031 2. Institute of Electric and Information Technology, Anhui University of Science and Technology, Huainan, China, 232001 Abstract: A method of thermostatic control of LED as light source for differential optical absorption spectroscopy (DOAS) measurements is present. A peltier is used to control LED’s temperature and its working current is regulated through PID algorithm in order to keep LED’s temperature constant. Hardware design and software flow of thermostatic control system is demonstrated in detail, and the thermostatic control effect and stability of LED’s spectrum are tested. The test results show that the impacts of ambient temperature on the control effect are effectively restrained and ±0.1℃ of control accuracy is obtained. Compared with the LED without thermostatic control under the same condition, the residual noise of the LED with thermostatic control is markedly lower, which also proves the availability of this method. Key words: LED, DOAS, thermostatic control, PID algorithm 0 引言 DOAS技术最初由Platt等人[1]提出，经过一段时间的发展，目前已成为大气污染监测的常用方法之一，它具有监测范围广、响应速度快、无接触测量以及可实现多组份同时在线监测等特点，在对流层痕量气体监测中有着广泛应用[2-4]。DOAS技术是利用大气中气体分子的窄带吸收特性来鉴别气体成份，并根据窄带吸收强度来反演微量气体的浓度，其定量关系可由Lambert-Beer定律给出[5]。根据采用光源的不同，可分为主动DOAS 和被动DOAS。被动DOAS 以自然光为光源，太阳光、月光和星光均可作为被动DOAS的光源；主动DOAS 则利用人工光源作光源，目前主要是氙弧灯、氘灯等。 与氙弧灯相比，LED具有体积小、寿命长、安全可靠、价格便宜、节能环保等优势，而且近年来随着LED技术的发展和不断改进，不仅可见LED变得更加明亮，发光效率变得更高，紫外波段的LED也已经商品化。采用LED作为主动DOAS的