剩余污泥在混合碱条件下发酵回收碳源和氮磷元素.docVIP

第 44 卷第 7 期 2013 年 7 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.7 July 2013  剩余污泥在混合碱条件下发酵回收碳源和氮磷元素 苏高强，汪传新，彭永臻 (北京工业大学北京市水质科学与水环境恢复工程重点实验室， 北京市污水脱氮除磷处理与过程控制工程技术研究中心，北京，100124) 摘要：在 35 和 pH=10 的条件下，考察剩余污泥在 NaOH，Na3PO4，NaOH+Na3PO4 碱性条件下水解和产酸性能， 以及剩余污泥发酵液中氨氮和正磷酸盐的回收情况，并计算回收剩余污泥中碳源和氮磷元素的成本。研究结果表 明：剩余污泥在这 3 种碱性条件下具有较为相近的水解和产酸能力。但在 NaOH+Na3PO4 碱性条件下，剩余污泥 发酵液中的磷酸盐和氨氮的摩尔比最接近 1:1，因此最适合以磷酸铵镁沉淀的方式回收。使用 NaOH+Na3PO4 控制 污泥的 pH 发酵，回收发酵液中的氨氮和正磷酸盐的效果与 NaOH 碱性条件下的相当，但剩余污泥中碳源和氮磷 元素的回收成本在 3 种碱性条件下最低。因此，使用 NaOH+Na3PO4 控制剩余污泥 pH 发酵，可以优化回收剩余 污泥中碳源和氮磷元素的过程。 关键词：剩余污泥；水解酸化；碳源回收；氮磷元素；碱性环境 中图分类号：X703.1 文献标志码：A 文章编号：1672?7207(2013)07?3061?05  Recovery carbon source, nitrogen and phosphorus by fermenting waste activated sludge at mixed base condition SU Gaoqiang, WANG Chuanxin, PENG Yongzhen (Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, Engineering Research Center of Beijing, Beijing University of Technology, Beijing 100124, China) Abstract: The hydrolysis and acidification of waste activated sludge were investigated under three types of alkaline conditions, i.e. NaOH, Na3PO4 and combination of NaOH and Na3PO4. Temperature and pH were controlled at 35 ℃ and 10 respectively for all alkaline conditions investigated. Then the recovery of ammonia and phosphorus from the three types of alkaline fermentation liquid was conducted. Finally, the cost for recovering carbon source, ammonia and phosphorus was checked. The results show that the hydrolysis and acidification abilities of WAS under the three types of alkaline conditions are similar. Whereas, the molar ratio of phosphorus and ammonia is close to 1:1 under the alkaline condition which is controlled by combination of NaOH and Na3PO4, which benefits ammonia and phosphorus recovery in the form of struvite. The ammonia and phosphorus recovery efficiencies are equivalent when pH