磺化甲醛丙酮缩合型水泥分散剂.pdfVIP

磺化甲醛丙酮缩合型水泥分散剂 磺化甲醛丙酮缩合型水泥分散剂的研制 摘要 油井水泥分散剂是目前国内外使用最普遍、消耗量最大的油井水泥外加剂之一。本文以 甲醛和丙酮及亚硫酸钠为原料合成了一种新型的油井水泥分散剂——水溶性磺化丙酮- 甲醛 缩聚物。该类分散剂是 20 世纪 90 年代新近开发的新型分散剂，具有分散性能好，抗温抗盐 性好，与其他的外加剂配伍性好等特点。本文在前人研究的基础上开发了新的合成工艺，即 利用亚硫酸钠代替了以前的亚硫酸氢钠和氢氧化钠，使得工艺流程大大简化。 文中考察了亚硫酸钠的用量、醛酮比和反应时间等工艺条件对该产物分散性能的影响， 得出了反应的最佳物料配比和温度、时间等条件。研究表明该产品完全达到了油井水泥分散 剂的性能标准，说明该合成工艺是可行的。 关键词：磺化丙酮- 甲醛缩聚物 分散剂 油井水泥 磺化甲醛丙酮缩合型水泥分散剂 THE STUDY OF THE DISPERSANT FOR CEMENT SLURRIES THAT IS SULPHONATED ACETONE-FORMALDEHYDE POLYCONDENSATE Zhang Xiushen （Department of chemical engineering , Beijing institute of petro-chemical technology, 102617） ABSTRACT The dispersant for cement slurries has been becoming one of the most important additive for cement slurries now. In this article, a new polyelectrolyte, sulphonated acetone-formaldehyde polycondensate is synthesized by acetone, formaldehyde and sodium sulfite. This dispersant is developed in 1990s. It is well dispersed, heat-resistant, and so on. This article is a new technology that sodium sulfite takes the place of sodium bisulfite and sodium hydroxide. So the technology has become easier. In this article, we analyze the effect of the process condition to the reaction, for examples, the amount of sodium sulfite, the scale of formaldehyde and acetone, reaction time. The result shows that this dispersant has achieved good performance of the dispersant for cement slurries. This technology is feasible. Keywords：sulphonated acetone-formaldehyde polycondensate, dispersant, cement slurries 磺化甲醛丙酮缩合型水泥分散剂 目 录 1 引言……………………