纳米TiO2 光催化降解有机磷农药的研究[J].docVIP

文章编号：1008-181X（2001）03-0173-03 纳米TiO2光催化降解有机磷农药的研究 徐悦华1，古国榜1，伍志锋2，李芳柏3，万洪富3 （1：华南理工大学化工学院，广东 广州510640；2：广东江门环境保护局，广东 江门；3：广东省生态环境与土壤研究所，广东 广州 510650） 摘要：通过实验，探讨了用纳米TiO2光催化处理有机磷农药模拟废水和实际应用的有机磷农药的可行性。实验表明，以测定不同时间PO43-的浓度来衡量有机磷的降解率，并以此来衡量有机磷农药及其中间产物降解的程度是合理的。光催化降解甲胺磷和水胺硫磷的结果，显示了有机磷农药的降解率与其结构有关。实际应用的有机磷农药也可用光催化降解。 关键词：甲胺磷；光催化降解；有机磷农药；纳米TiO2 中图分类号：X592 文献标识码：A Study on photocatalytic degradation of organophosphorous pesticides with TiO2 nanometre powder XU Yue-hua1, GU Guo-bang1, WU Zhi-feng2, LI Fang-bai3, WAN Hong-fu3 （1: College of Chemical Industry, South China University of Technology, Guangzhou 510640, China；2: Jiangmen Environmental Protection Bureau, Jiangmen, China；3: Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650, China） Abstract: The photocatalytic degradation of organophosphorous pesticides and commercial organophosphorous pesticides by TiO2 nanometre powder was studied in this paper. It is showed that the degradation efficiency of methamidophos indicating by PO43-is better than indicating by methamidophos. This method is not only convenient but also showing the degree of complete degradation of organophosphorous pesticides and intermediates. It is showed that the degradation efficiency of organophosphorous pesticides is related to their structure by the photocatalytic degradation of methamidophos and isocarbophos. The order of photocatalytic degradation of commercial organophosphorous pesticides is not coincident with that of pure organophosphorous pesticides, because the commercial organophosphorous pesticides contain a large mount of solvents. It is proved by the result of photocatalytic degradation of pure methamidophos and commercial methamidophos. Key words: methamidophos; photocatalytic degradation; organophosphorous pesticides; TiO2 nanometre powder有机磷农药是世界上生产和使用得最多的农药品种。为了减少农药的污染，农药生产过程中排放的废水，以及贮槽、贮罐的洗涤废水都需要处理[1]。目前，有机磷农药的降解研究一般都以细菌[2]或真菌[3]为降解媒介，而且国内普遍采用稀释生化法处理有机磷农药废水，但这种方法存在着稀释倍数高（20~40倍）、、[4]。而光催化法是用光激发催化