疏水催化剂用PtC催化剂的制备方法.pdfVIP

化学通报 2006 年 第69 卷 w100 疏水催化剂用 Pt/C 催化剂的制备方法 胡胜 朱祖良 罗顺忠 王和义 罗阳明 (中国工程物理研究院核物理与化学研究所 绵阳 621900) 摘 要 Pt/C 催化剂制备是制备Pt/C/PTFE 类型疏水催化剂的关键步骤之一。本文对用于Pt/C 催化 剂制备的主要碳载体进行了综述，重点对活性碳和碳黑的性质进行了比较。碳黑有疏水性强、微孔结构少、 容易制备高分散度催化剂的优点。概述了几种主要的 Pt/C 催化剂制备方法的研究进展，比较了不同制备 方法的优缺点。分析了纳米 Pt/C 催化剂与单纯纳米材料制备的差异，纳米材料制备通过外加保护剂或修 饰剂阻止纳米粒子团聚，而催化剂制备还可利用载体效应抑制活性金属粒子团聚。将纳米材料制备方法中 抑制粒子粒径长大的方法和载体作用结合，有助于制备高分散度催化剂。 关键词 疏水催化剂 Pt/C 催化剂 炭载体 制备方法 纳米催化剂 Preparation Methods of Pt/C Catalysts for Hydrophobic Pt/C/PTFE Catalysts Hu Sheng, Zhu Zuliang, Luo Shunzhong, Wang Heyi, Luo Yangming (Institute of Nuclear Physics and Chemistry, CAEP, Mianyang 621900) Abstract Preparation of Pt/C catalyst is one of the key processes of preparation of hydrophobic Pt/C/PTFE catalyst. Carbon carriers of Pt/C catalysts were reviewed, and activated carbon and carbon black were principally analyzed. Carbon black has better hydrophobicity, less micro-hole, and more dispersed Pt. Several kinds of preparation methods of Pt/C catalysts were summarized, and the advantages and disadvantages of these preparation methods were analyzed. At last, the differences of preparation methods of nano-Pt/C catalysts and nano-materials were compared. The protector or modifier could hold back the increase of particle sizes when nano-materials were prepared. While the catalysts are prepared, the catalysts carrier could also hold back the conglomeration of active metal particles. It is instrumental in the preparation of high-dispersed catalysts to combine