盐酸硫胺修饰的CdSe聚乙二醇纳米微球的制备和荧光光谱.pdfVIP

第32卷第2期　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 中南民族大学学报(自然科学版)　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 　 Vol.32 No.2 2013年6月　 　 　 　 　 　 　 　 　 　 　 Journal of South-Central University for Nationalities(Nat.Sci.Edition)　 　 　 　 　 　 　 　 　 　 Jun.2013 盐酸硫胺修饰的CdSe/ 聚乙二醇纳米微球的 制备和荧光光谱 詹国庆,王晴晴 (中南民族大学 化学与材料科学学院国家民委分析化学重点实验室 武汉430074) 摘　 要　 应用一锅法合成了盐酸硫胺修饰的CdSe/ 聚乙二醇纳米微球,并将纯化后的产物进行了红外(FTIR)表 征,X-射线光电子能谱(XPS)分析,透射电子显微镜(TEM)形貌分析及荧光分析.FTIR和XPS证实了盐酸硫胺对 纳米微球的修饰,TEM显示微球呈球状,具有良好的分散性,在515nm左右发射荧光.合成最佳条件为:pH11,Cd与 盐酸硫胺的摩尔比为1 ︰8,40℃回流2h. 关键词　 盐酸硫胺;纳米微球;荧光光谱 中图分类号　 TQ316.3;O621.3　 文献标识码　 A　 文章编号　 1672-4321(2013)02-0013-04 Preparation and Fluorescence Spectra of Thiamine Hydrochloride Modified CdSe/ Polyethylene Glycol Nanospheres Zhan Guoqing,Wang Qingqing ( Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission, College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan430074,China) Abstract　 Thiamine hydrochloride-capped CdSe/ polyethylene glycol nanospheres were synthesised via one-pot technique. The nanosphereswere characterized by FTIR,XPS,TEM and fluorescence spectra. FTIR and XPS analysis confirmed the capping of the nanoparticles by the thiamine hydrochloride. TEM image displayed that the nanospheres were small and spherical in shape with good dispersion. The fluorescence spectra illustrated that the nanospheres exhibited emission at = about515nm. Optimum condition for synthesis is pH 11,40 ℃ for2h and n(Cd)/ n(thiamine hydrochloride) 1 ︰8. Keywords　 thiamine hydrochloride;nanospheres;fluorescence spectra 　 　 量子点(QDs)是显示量子尺寸效应的半导体纳 量子