CVD金刚石薄膜在钨丝和碳纤维上的制备.pdfVIP

第 卷第 期 功能材料与器件学报 7 3 Vol. 7, No. 3 年 月 200 1 9 JOURNAL OF FUNCTIONAL MATERIALS AND DEVICES Sept., 200 1 ( ) Article ID 1007 - 4252 200 1 03 - 0235 - 05 Preparation of CVD diamond coatings on W wire and C fiber HE Xian - chang, SHEN He - sheng, ZHANG Zhi - ming, HU Xiao - jun, YANG Xiao - qian, WAN Yong - zhong ( State Key Lab of MMCM ’ s, Shanghai Jiaotong University, Shanghai 200030, China ) Abstract Diamond growth on W - wire and C - fiber substrates was studied. A treatment was used to separate fibers one by one from a bunch of more than 10000 fibers. The selected growth condition was to keep the carbon fiber core solid after CVD growth. Activation energy of CVD coated fibers is 93. 15 kJ / mol in average. SEM pictures show surface and core morphology of the coatings under different treatment conditions. There are two different contrasts related to interior graphite carbon and exterior diamond layer. Wire fracture strength and Young ’ s modulus measurement indicates that the fracture strength of W wire with diamond coating is 0. 567 GPa, very close to its value without coating. However, the fracture strain of the wire with diamond coating is 4. 8% , which is much less than that of W wire fracture strain of 7% . It means that diamond coated wire may reduce wire fracture strain and improve its mechanical property. Key words CVD diamond;