矿渣微晶玻璃的析晶行为与性能.pdfVIP

第 17 卷第 2 期 中国有色金属学报 2007 年 2 月 Vol.17 No.2 The Chinese Journal of Nonferrous Metals Feb. 2007 文章编号：1004-0609(2007)02-0341-07 矿渣微晶玻璃的析晶行为与性能 史培阳，张 影，张大勇，王媛媛，姜茂发 (东北大学 材料与冶金学院，沈阳 110004) 摘 要：以铁尾矿、硼泥和粉煤灰制备矿渣微晶玻璃，利用 X 射线衍射仪、扫描电镜和穆斯堡尔谱对微晶玻璃的 微观结构进行研究。结果表明：矿渣微晶玻璃的主析晶相为钙铁辉石，次晶相为普通辉石和紫苏辉石；随着硼泥 配入量的增加，矿渣微晶玻璃中晶体的析出量和尺寸均逐渐增加，晶体形态由枝晶向球晶及块状晶体过渡；枝晶 向球晶转变可以明显改善矿渣微晶玻璃的性能，而球晶向块状晶体的转变则恶化了微晶玻璃的性能。在本实验研 究的条件下，Fe2+主要分布在析晶相中，起到促进晶体析出的作用；随着硼泥配入量的增加，Fe3+含量也逐渐增 加，Fe2+和 Fe3+共同促进了熔体内部的晶体析出。 关键词：微晶玻璃；铁尾矿；微观组织；穆斯堡尔谱 中图分类号：TQ 171 文献标识码：A Crystallization behavior and properties of glass ceramic of ferrous tailings and slag SHI Pei-yang, ZHANG Yi, ZHANG Da-yong, WANG Yuan-yuan, JIANG Mao-fa (School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China) Abstract: The slag glass-ceramic was prepared from ferrous tailing, boron mud and fly ash. The microstructure of glass-ceramic was investigated by X-ray diffractometry, scanning electron microscope and Mössbauer spectrum. The results show that, Main crystallization phase of glass ceramic was hedenbergite, and the minor crystallization phases were augite and hypersthene. With increasing boron mud addition, the amount and the size of crystallization phases both gradually increased, the configure of crystallization phases transformed from the branch, the ball, to the block. The transformation from the branch to the ball could improve the properties of glass ceramic, and the transformation from the