煤制烯烃技术进展.pptVIP

中国煤制烯烃技术进展Coal-to-Olefin Technology in China 刘中民 Zhongmin Liu 中国科学院大连化学物理研究所 Dalian Institute of Chemical Physics, Chinese Academy of Science zml@dicp.ac.cn 2009.12.03 内容 Content 背景 Background 甲醇制乙烯和丙烯 Methanol to Ethylene and Propylene DMTO技术 DMTO technology 技术经济 Economics 工业化 Commercialization 甲醇制丙烯 Methanol to Propylene FMTP技术 FMTP technology 甲醇：联系煤化工与石油化工的桥梁Methanol: an important product linking petrochemicals to coal chemical industry 烯烃生产技术路线和MTO Technical Routes for Olefin Production MTO MTO反应特点Characteristic of Methanol to Olefin reaction 酸性催化特征 Acid catalyzed reaction 高转化率：100% High conversion 低压反应 Low pressure is favorable to light olefin selectivity 强放热 Exothermic reaction 400-500oC，100% conversion ?H = -22.4～-22.1 KJ/mol methanol 快速反应 Fast reaction 100% conversion at 0.04s contact time 分子筛催化的形状选择性效应：高选择性 Shape selective effect should be applied for high olefin selectivity First generation of catalyst: Modified ZSM-5 Small pore SAPO molecular sieve could be good candidate for developing new catalyst 大连化物所DMTO研究历程DMTO RD in DICP DMTO技术 SAPO分子筛的研究DMTO technology Research on Small pore SAPO molecular sieves 早期专利 UCC patent in 1982 (USP4440871) on SAPOs DICP首次报道了SAPO-34对MTO的优异性能 DICP first demonstrated good performance of SAPO-34 in MTO reaction Applied Catalysis，Vol.40, No1-2，p316，1988 ；Applied Catalysis, vol.64，p31-40, 1990 DICP对SAPO分子筛的合成及机理进行了系统深入的研究 Synthesis and mechanism were well studied on small pore SAPO molecular sieves 集中于SAPO-34 Focused on SAPO-34 其他小孔SAPO分子筛 Other small pore SAPOs were also synthesized and tested SAPO-34分子筛SAPO-34 Molecular Sieve SAPO-34合成方法的创新New methods for SAPO-34 synthesis SAPO-34的晶化机理Crystallization mechanism of SAPO-34 SAPO-34的晶化机理Crystallization mechanism of SAPO-34 晶化过程中Si在晶粒中的非均匀分布模型 Schematic diagram of crystallization process with Si distribution in the crystals 流化催化剂研制Development of fluidized catalyst DMTO Demonstration 目标 Objective 通过工业性试验，开发我国自有知识产权的DMTO 工业化成套技术，为建设以煤为原料生产低碳烯烃的工业化装置奠定