SiC颗粒尺寸对镍基复合镀层耐磨性和耐蚀性的影响.pdfVIP

第 20 卷第 1 期 中国有色金属学报 2010 年 1 月 Vol.20 No.1 The Chinese Journal of Nonferrous Metals Jan. 2010 文章编号：1004-0609(2010)01-0125-07 SiC 颗粒尺寸对镍基复合镀层耐磨性和耐蚀性的影响 吴俊升，李晓刚，孔 明，董超芳 (北京科技大学 新材料技术研究院 腐蚀与防护中心，北京 100083) 摘 要：在正交实验基础上，对比研究微米 SiC(平均粒径 1.5 μm)和纳米 SiC(平均粒径 20 nm)增强复合镍基镀层 的摩擦磨损行为和耐腐蚀性能。通过TEM、SEM、EDX 和 XRD 等手段研究颗粒分散状态以及复合镀层的表面和 截面形貌、成分及相结构。采用球−盘滑动摩擦磨损试验机研究复合镀层的耐磨性。电化学阻抗谱测量在 3.5%的 NaCl 水溶液中进行。结果表明：微米级颗粒增强复合镀层可以获得更高的表面硬度，两种增强复合镀层具有相似 的摩擦磨损行为。电化学阻抗谱分析表明：SiC 颗粒的加入可以提高镀层的耐腐蚀性，且纳米颗粒复合镀层具有 更好的耐蚀性。 关键词：复合镀层；镍；SiC 颗粒；耐磨耐蚀性能 中图分类号：TG 153.2 文献标识码：A Influence of SiC particle size on wear and corrosion resistance of electrodeposited Ni- SiC composite coatings WU Jun-sheng, LI Xiao-gang, KONG Ming, DONG Chao-fang (Corrosion and Protection Center, Institute of Advanced Materials, University of Science and Technology Beijing, Beijing 100083, China) Abstract: Ni-SiC composite coatings were prepared by the co-electrodeposion of Ni matrix with micron and nano-sized SiC particles (1.5 μm and 20 nm), respectively. The microstructure, hardness, tribological properties and corrosion behaviours of the composite coating on medium carbon steels were investigated. The results indicate that the incorporation of SiC particles in metallic matrix significantly improves the hardness and wear resistance of deposited layer. Moreover, the hardness of the composite coatings is much more improved by the micron-particles than by the nano-sized ones, while there is al