二聚酸改性丙烯酸酯耐水乳液合成.pdfVIP

全国中文核心期刊 二聚酸改性丙烯酸酯耐水乳液的合成 孙翔月，郭文迅，袁华，高鹏 （湖南大学材料科学与工程学院，湖南 长沙 410082） 采用新型功能单体二聚酸，通过半连续种子乳液聚合法制得了性能优异的纳米级改性丙烯酸酯乳液。考察了二聚酸用 摘要： 量对乳胶膜性能的影响，并采用粒径分析、DSC、FTIR 分析对其进行表征。结果表明，在引入二聚酸单体用量为6.5% ，复合乳化剂用 量为2.3% ，引发剂用量为0.7%时，合成的微乳液固含量达46.6% ，粒径在90 nm 左右，并具有分布窄的特点。合成的乳液可实现室 温交联，涂膜硬度高，综合性能好，尤其耐水性得到了很大提高。 二聚酸；乳液聚合；纳米级乳液；吸水率 关键词： 中图分类号：TQ331.4 文献标识码：A 文章编号：1001-702X （2009）10-0006-05 Preparation of waterproof acrylate emulsion modified by dimer acid SUN Xiangyue ，GUO Wenxun，YUAN Hua，GAO Peng （College of Material Science and Engineering ，Hunan University ，Changsha 410082 ，Hunan ，China） Abstract:An acrylic nano-emulsion was produced with new functional monomer dimer acid through semi-continuous seed emulsion polymerization method. The influence of addition of dimer acid on the properties of latex film was investigated and its characteristics were represented by particle size analysis ，DSC and FTIR analysis. The results showed that when the introduced percentage of dimer acid ，compound emulsifier and initiator is 6.5% ，2.3% ，and 0.7% respectively ，solid content of synthesized micro -emulsion reached 46.6% ，the particle size is determined around 90 nm and the distribution is narrow. The synthesized emulsion can be cross-linked at room temperature ，with high film hardness ，good overall performance ，and particularly higher water resistance has been greatly improved. Key words:dimer acid ；emulsion polymerization ；nano-emulsion ；water absorption 聚酸（二聚酸含量＞90%）是化工行业的重要中间体，是合成聚 0 引 言 酰胺树脂的重要原料，广泛应用于油墨、涂料、热熔添加剂、功