胞外聚合物同铁离子交互作用及对微生物分解黄铁矿的影响.pdfVIP

中国科技论文在线 胞外聚合物同铁离子交互作用及对微生物 分解黄铁矿的影响# 虞艳云，李明明，彭书传，李青，周跃飞，陈天虎，岳正波** 5 （合肥工业大学资源与环境工程学院，合肥230009） 摘要：本实验研究了不同pH 下，Fe3+ 同嗜酸氧化亚铁硫杆菌(Acidithiobacillus ferrooxidans ， 简称A . f )胞外聚合物（Extracellular Polymeric Substances ，简称EPS ）交互作用及对黄铁矿 分解的影响。通过Zeta 电位和循环伏安法分析测试研究了EPS 与含铁EPS 溶液的电化学性 10 质，发现在低pH 下EPS 与含铁EPS 呈正电荷性，易于吸附在呈负电荷性的黄铁矿表面， 并且含铁EPS 溶液更有利于黄铁矿的氧化反应。黄铁矿分解实验结果表明pH 较低时EPS 对Fe3+ 氧化分解黄铁矿的促进效果不明显，在pH 较高时EPS 能明显增强Fe3+ 对黄铁矿的分 解作用。 关键词：胞外聚合物；Fe3+ ；黄铁矿；pH ；Zeta 电位；循环伏安曲线 15 中图分类号：P578. 2+ 92;Q939. 99 Interaction of extracellular polymeric substances and Fe3+ and its effect on microbial decomposition of pyrite YU Yanyun, LI Mingming, PENG Shuchuan, LI Qing, ZHOU Yuefei, CHEN Tianhu, 20 YUE Zhengbo (School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009) Abstract: This study investigated the interaction of Fe3+ and extracellular polymeric substances (EPS) of Acidithiobacillus ferrooxidans and its effect on microbial decomposition of pyrite under different pH. 25 The electrochemical characteristic of EPS and iron-containing EPS were analyzed by the measurement of Zeta potential and cyclic voltammetry curves. Results showed that both EPS solution were positively charged at lower pH and could be easily attached to the negatively charged surface of pyrite, and iron-containing EPS solution is more conducive to the oxidation reaction of pyrite. Experimental results of the pyrite decomposition indicated that the promoting effect of EPS on the decomposition 30 process of pyrite oxidized by Fe3+ was not obvious at lower pH,