褐煤低温氧化改性的研究.pdfVIP

中国科技论文在线 褐煤低温氧化改性的研究 张增志，刘肖宇* （中国矿业大学（北京）生态功能材料研究所，北京 100083） 5 摘要：为了增加宝日希勒褐煤表面酸性官能团的含量，提高其吸附能力，将其从块状制成细 煤粉，并使其在不同条件下进行空气通风氧化。使用 Boehm 滴定法测定未添加催化剂样品 氧化后羧基和酚羟基含量的变化，用傅里叶变换红外光谱法测定添加催化剂样品氧化后官能 团含量的变化。结果显示，褐煤中羧基和酚羟基含量在低温氧化时随氧化温度的升高而增加， 在 180℃时，羧基含量随氧化时间延长而增加，酚羟基含量则出现降低。添加催化剂后，褐 10 煤氧化后生成的总酸性官能增加，等离子质量的条件下，钠离子和钙离子催化效果较好，钾 离子也有一定催化作用。 关键词：煤化工工程；褐煤；低温氧化 中图分类号：TQ531.6 15 THE RESEARCH ON LOW TEMPERATURE MODIFICATION OF LIGNITE BY OXIDATION Zhang Zengzhi, Liu Xiaoyu (Research Institute of Ecological and Functional Material, China University of Mining Technology, Beijing 100083) 20 Abstract: In this paper the Baorixile lignite was made into powder and oxidized under different conditons to increased the content of acid functional groups on the surface of powder so that the adsorption capacity of lignite can be improved.The Boehm titration was used to determine the change of carbonxyl and phenol hydroxyl content after oxiditzation without catalyst,the Fourier Transform infrared spectroscopy was used to determine the change of functional groups after 25 oxidation with catalyst.The content of carbonxyl and hadroxyl in lignite was increased with the temperature,duiring 180 ℃，the content of carbonxyl increased with the oxidation time while the phenol hydroxyl decreased.The total acid groups increased when the catalyst was added,the sodium ion and calcium ion had better effect of catalysis while the potassium had so