ZnOZnFe2O4纳米粒子的制备及其光催化特性研究.pdfVIP

ZnO/ZnFe2O4纳米粒子的制备及其光催化特性研究 刘鹤 李金华 方铉 方芳 楚学影 魏志鹏 李霜 王菲王晓华 长春理工大学理学院，长春 130022 摘要：本文利用水热法结合高温退火的方法制备了ZnO/ZnFe2O4纳米粒子。用扫描电子显微镜(SEM）、X射线衍射(XRD)、光致 发光光谱(PL)对退火前后的ZnO/ZnFe2O4纳米粒子进行表征。XRD与SEM结果表明，制备的纳米粒子主要由六角纤锌矿结构 的ZnO和立方结构的ZnFe2O4构成，退火后晶体质量明显变好，粒径平均135nm左右。PL观察到退火后，与ZnO带隙相关的 发光强度明显降低。这是由于ZnO/ZnFe2O4形成了type-II能带异质结实现了光生载流子的分离的结果。最后以甲基橙为目标污 染物，退火后的ZnO/ZnFe2O4纳米粒子4h的降解率为60.32％。因此，具有载流子分离能力的ZnO/ZnFe2O4纳米粒子在光催化 领域有很好的发展前景。 关键词: ZnO；ZnFe2O4；纳米复合结构；载流子分离 O472.3 A TheGrowthandPhotocatalyticPropertyofZnO/ZnFe2O4 Nanoparticles HeLiuJinhuaLiXuanFangFangFangXueyingChuZhipengWeiShuangLiFeiWang XiaohuaWang ChangchunUniersityofScienceandTechnology,Changchun,130022,China Abstract:Inthispaper,ZnO/ZnFe204nunoparticlesweresynthesizedbyhydrothermalandannealedmethod.X-raydiffraction(XRD), scanningelectronmicroscopy(SEM)andphotoluminescence(PL)spectroscopywereusedtocharacterizetheas-synthesizedandannealed ZnO/ZnFe2O4nanoparticles.Theresultsindicatedthattheas-synthesizednanoparticlesmainlycomposedofhexagonwurtziteZnOand cubicZnFe2O4,andthecrystalqualitywasimprovedbyannealingtreatment.Inaddition,partsofFe203reactedwithZnOandformed ZrtFe2O4.Theparticalsizeofas-annealedZnO/ZnFe2O4nanoparticleswas135nmaveragely.Andmorenotably,itisobservedthatthe intrinsicphotoluminescenceattributedtotherecombinationofphotogcneratedcaRriersofas-annealedZnOwasobviouslyweakened, whichconfermsthataZnO/ZnFe2O4heterojunctionwasformedwhichcouldimprovetheseparationofphotogeneratedcarriers.Asa result,therewouldbemoreelectronsandholestoparticipateinphotocatalyticprocesses.Inaddition,Weinvestigatedphotoeatalytic propertiesofas-annealedZnO/ZnFe2O4nanoparticlesundertheUVlight.ThephotocatalyticdegradationratioofMOwas60.32％under 4hoursillumination.Inconclusion,as-annealedphotogeneratedcarriersseparableZnO/