氧化石墨烯纳米氧化铁复合物的制备及其对砷吸附性能.pdfVIP

氧化石墨烯/纳米氧化铁复合物的制备及其对砷吸附性能 摘 要 以改进的 Hummers 方法制备了氧化石墨烯。在适量浓硫酸中，投入石墨、 硝酸钠和高锰酸钾为原料，制备得理想的氧化石墨烯。采用 FT-IR、TG、TEM、 XRD 对氧化石墨烯的结构和性能进行了表征。 2+ 3+ 以氯酸钠为氧化剂氧化绿矾制备纳米氧化铁。通过实验得到Fe 转化为Fe 和α-FeOOH 制备的最佳条件，制得色泽较好、尺寸最好纳米氧化铁。采用 FT-IR、 TG、TEM、XRD 对其结构和性能进行了表征。 将氧化石墨烯与纳米氧化铁通过超声剥离和直接插入法制备复合物。并用 FT-IR、TG、TEM、XRD 对复合物的结构和性能进行了表征。 复合物对砷吸附的研究。为了使吸附达到充分平衡，研究不同浓度的含砷溶 液选择吸附方式，分别得到高砷溶液和低砷溶液的最佳超声吸附时间和静止吸 附时间。与其他吸附材料相比本材料的优点：(1)高效，对砷吸附性比活性炭、 羟基氧化铁高的多。(2)化学稳定好，氧化石墨烯、纳米氧化铁的羟基交联物和 砷盐形成具有很强机械强度的化合物。(3)经济环保，原材料来源广泛，易于制 取，且吸附效果良好，不会导致水的二次污染。 关键词：氧化石墨烯，纳米氧化铁， 合成复合物，对砷吸附性能 Praperation of graphene oxide/nano-ferric oxide compound and its adsorption properties for arsenic ABSTRACT Graphene oxide was prepared by the modified Hummers methods. Ideal product was abtained by the reaction of graphite, Sodium nitrate and potassium permanganate in concentrated sulphuric acid. The structure and property were characterized by FT-IR . TG .TEM and XRD. LuFan was oxidized by sodium chlorate to prepare nonameter iron oxide. The optimal experiment condition of Fe2+ to Fe3+ and the preparation α—FeOOH was researed , the colour and dimension of nonameter iron oxide were both good. The structure and property were characterized by FT-IR .TG .TEM and XRD . Composite material was prepared by oxidation graphite and nano ferric oxide through the methods of ultrasound stripping and direct plug-in. The structure and property were characterized by FT-IR . TG .TEM and XRD . The adsorption research of Composite materials for arsenic. To reach the full adsorption balance, the selective adsorption pattern of different concentration of arsenic solution were researched to obtain the optimal oscillation adsorption