草甘膦分析文摘1070篇.doc

1071-83-6 →分析，杂质，光谱特性，性质 ID：24 lxy 草甘膦分析类文献 1.Microscale solid phase extraction of glyphosate and aminomethylphosphonic acid in water and guava fruit extract using alumina-coated iron oxide nanoparticles followed by capillary electrophoresis and electrochemiluminescence detection ByHsu, Chia-Chen; Whang, Chen-Wen FromJournal of Chromatography, A (2009), 1216(49), 8575-8580. Language: English, Database: CAPLUS A microscale solid-phase extn. (SPE) method using alumina-coated iron oxide nanoparticles (Fe3O4.Al2O3 NPs) as the affinity adsorbent for glyphosate (GLY) and its major metabolite aminomethylphosphonic acid (AMPA) in aq. soln. is reported. One milligram of Fe3O4@Al2O3 NPs was employed to ext. both analytes in 5 mL of aq. soln. After 5 min extn., magnetic NPs were isolated from sample soln. by employing an external magnet. Followed by rinsing the NPs with 5 μl of 20 mM Na4P2O7 soln. for 5 min, the ext. was directly analyzed using the derivatization-free CE-electrochemiluminescence (CE-ECL) method. With a sample-to-ext. vol. ratio of 1000, the enrichment factors for GLY and AMPA were 460 and 64, resp. The limits of detection (LODs) were 0.3 and 30 ng ml-1 for GLY and AMPA in water, resp. The developed method was applied to the anal. of GLY in guava fruit. The LOD of GLY in guava was 0.01 μg g-1. Total anal. time including sample pretreatment, SPE and CE-ECL was less than 1 h. Substances Reactions Citing Full Text Link 0 Comments 0 Tags 2.Glyphosate and glufosinate detection at electrogenerated NiAl-LDH thin films ByKhenifi, Aicha; Derriche, Zoubir; Forano, Claude; Prevot, Vanessa; Mousty, Christine; Scavetta, Erika; Ballarin, Barbara; Guadagnini, Lorella; Tonelli, Domenica FromAnalytica Chimica Acta (2009), 654(2), 97-102. Language: English, Database: CAPLUS An amperometric sensor based on Ni1-xAlx(OH)2NO3x·nH2O layered double hydroxide (LDH) has been developed for the electrochem. anal. in one step of two herbicides: glyphosate (