煤矿区废水中溶解性有机质与铜的结合特性.pdfVIP

中国环境科学 2013,33(8) ：1433~1441 China Environmental Science 煤矿区废水中溶解性有机质与铜的结合特性 冯启言 1*,张 彦 2,孟庆俊 1 (1. 中国矿业大学环境与测绘学院,江苏 徐州 221116 ；2.天津市环境保护科学研究 院,天津 300191) 摘要：为研究煤矿区废水排放对环境中重金属化学行为的影响,通过荧光滴定实 ,利用铜离子选择电极法和荧光猝灭法定量化研究了矿 井水和生活污水中溶解性有机质对铜的结合行为.结果表明,铜离子选择性电极法能精确地定量化这 2 类废水中有机质对铜的结合容量,其 中矿井水中有机质对铜具有较大的结合容量,可以达到 163.9mg/g,而生活污水中有机质对铜的结合容量相对较小,只有 72.6mg/g.荧光猝灭 法结果表征了这 2 类废水中各个组分对铜的结合特性,其中矿井水中的富里酸(A 峰)对铜具有较强的结合容量,而生活污水中的类蛋白组分 对铜的结合能力相对较弱.2 类废水与铜结合前后的红外光谱变化结果表明矿井水中腐殖酸物质与铜的结合是一种化学反应,其中的酚羟 基和羧基等官能团参与了反应,但生活污水中类蛋白物质的官能团与铜并没有发生化学结合反应. 关键词：溶解性有机质；结合特性；离子选择电极；荧光猝灭；定量化 中图分类号：X524 文献标识码：A 文章编号：1000-6923(2013)08-1433-09 Quantitative characterization of Cu binding potential of dissolved organic matter in wastewater of mining area. 1∗ 2 1 FENG Qi-yan , ZHANG Yan , MENG Qin-jun (1.School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, China ；2.Tianjin Academy of Environmental Science, Tianjin 300191, China). China Environmental Science, 2013,33(8)：1433~1441 Abstract ：In order to study the influence of the two wastewaters on the environmental behavior of heavy metals, a titration experiment was adopted to quantitatively characterize the interaction between Cu and DOM in mine water and domestic wastewater in a mining area using an ion-selective electrode and fluorescence quenching technology. The results showed that the Cu ion-selective electrode accurately characterized the complex capacity of DOM for Cu (II). The mine water had a high complex capacity for Cu, which accounted for 163.9mg/g, whereas the domestic wastewater had a low complex capacity, which was only 72.6mg/g. The fluorescence quenching results provided informa