千岛湖表层沉积物中多环芳烃污染特征及生态风险评价.pdfVIP

中国环境科学 2014,34(1) ：253~258 China Environmental Science 千岛湖表层沉积物中多环芳烃污染特征及生态风险评价 张 明 1*,唐访良 1,吴志旭 2,陈 峰 1,程新良 2,徐建芬 1,俞雅雲 1 (1.杭州市环境监测中心站,浙江 杭州 310007 ；2.淳安县环境监测站,浙江 杭州 311700) 摘要：利用高效液相色谱法对采集于 2012 年 12 月的部分千岛湖表层沉积物中多环芳 (PAHs)进行了分析.结果表明,千岛湖表层沉积物 中共检出属于美国EPA 优先控制 16 种 PAHs 中的 15 种,各采样点位 PAHs 总量的浓度范围在 258~906ng/g(干重)之间,平均值为 558ng/g, 属低污染水平.空间分布特征受周边区域内点源污染和河流输入污染物影响.沉积物中的多环芳烃以高分子量组分为主,通过特征组分比例 可确认其主要来源于周边地区煤炭、木材不完全燃烧及车船尾气排放.利用沉积物质量基准法、沉积物质量标准法分别对千岛湖表层沉积 物中 PAHs 的风险评价表明,千岛湖沉积物中不存在严重的多环芳烃生态风险,但部分点位按照质量标准法评价已经超过临界效应浓度值, 需加强监测查明污染源,并采取措施控制污染物输入. 关键词：多环芳烃；沉积物；千岛湖；污染特征；生态风险评价 中图分类号：X131 文献标识码：A 文章编号：1000-6923(2014)01-0253-06 Pollution characteristics and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments 1* 1 2 1 2 from Xin’anjiang Reservoir. ZHANG Ming , TANG Fang-Liang , WU Zhi-Xu , CHEN Feng , CHENG Xin-liang , XU Jian-Fen1, YU Ya-yun1 (1.Hangzhou Environmental Monitoring Central station,Hangzhou 310007, China ；2.Chun’an Environmental Monitoring Station, Hangzhou 311700, China). China Environmental Science, 2014,34(1)：253~258 Abstract ：Polycyclic aromatic hydrocarbons (PAHs) were quantitatively determined by HPLC in several surface sediment samples collected in December 2012 from Xin’anjiang Reservoir. The results showed that 15 of the 16 US EPA priority controlled PAHs were detected. Total concentrations of PAHs in surface sediments of the studied reservoir ranged from 258 to 906ng/g dry weight (dw), with average 558ng/g dw, lower pollution level. The distribution of PAHs is found to be influenced by riverine discharge and point-source pollution. The PAHs in the sediments were dominated by high molecular weight PAHs. According to the ratio of feature co