石化污水厂二级出水溶解性有机物分级解析研究.pdfVIP

中国环境科学 2012,32(11) ：2017~2022 China Environmental Science 石化污水厂二级出水溶解性有机物分级解析研究 孙青亮 1,2,吴昌永 2,胡 翔 1,周岳溪 2*,高 祯 3,徐 敏 3 (1.北京化工大学化学工程学院,北京 100029 ；2. 中国环境科学研究院水污染控制技术研究中心,北京 100012 ；3.河北工程大学城市建设学院,河北 邯郸 056038) 摘要：以某石化污水处理厂二级出水为研究对象,采用大孔吸附树脂将污水中溶解性有机物分离成亲水性物质、疏水酸性物质、疏水中性 物质和疏水碱性物质 4 个组分,分析了各组分的有机物的组成特征、三维荧光光谱特征及红外光谱特征.结果表明,亲水性物质和疏水酸性 物质分别占水样中溶解性有机碳的 49%和 29%,是该石化污水厂二级出水中的主要物质类别.亲水性物质中含有较多的生物源腐殖质类物 质,疏水中性物质含有较多的芳香族蛋白质和溶解性微生物代谢产物类物质.4 种组分的红外光谱图中 600~1200cm- 1 波数的指纹区波峰数 量最多,多为芳香类同分异构体化合物. 关键词：石化废水；溶解性有机物组分；紫外光谱；三维荧光光谱；红外光谱 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2012)11-2017-06 Classification and analysis of dissolved organic matter in the effluent of a petrochemical wastewater treatment plant. 1,2 2 1 2* 3 3 SUN Qing-liang , WU Chang-yong , HU Xiang , ZHOU Yue-xi , GAO Zhen , XU Min (1.Institute of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China ；2.Research Center of Water Pollution Control Technology, Chinese Research Academy of Environment Sciences, Beijing 100012, China ；3.Institute of Urban Construction, Hebei University of Engineering, Handan 056038, China). China Environmental Science, 2012,32(11)：2017~2022 Abstract ：Dissolved organic matter (DOM) in a biological effluent collected from a typical petrochemical wastewater treatment plant was isolated and fractionated using resin adsorption method. The fractions were operationally categorized as hydrophilic substances (HIS), hydrophobic acids (HOA), hydrophobic neutrals (HON), and hydrophobic bases (HOB). The dissolved organic carbon (DOC), specific UV absorbance, three dimensional excitation emission matrix fluorescence spectroscopy (3DEEM), ultraviolet spectrum and infra-red spectrum characteristics of the 4 fractions were analyzed. HIS and HOA were the main fractions and the