水解液出料和回流对秸秆水解产酸的影响.pdfVIP

中国环境科学 2013,33(11) ：2006~2012 China Environmental Science 水解液出料和回流对秸秆水解产酸的影响 * 陈广银, 吕利利,常志州 ,叶小梅,徐跃定,张建英 (江苏省农业科学院农业资源与环境研究所,农业部农村可再 生能源开发利用华东科学观测实验站,江苏 南京 210014) 摘要：为了解秸秆两相发酵水解相水解液出料和回流对秸秆水解产酸过程的影响, 以打捆麦秸为原料,在中温[(37±1)℃]条件下,采用批次进 料方式,进行秸秆水解产酸实验.实验设置水解液出料量为排空、排 1/2 和排 1/3,水解液回流频次为不回流、1d 回流 1 次和 3d 回流 1 次.结 果表明:水解液出料促进了秸秆有机物的水解溶出,水解液出料后秸秆中有机物大量水解溶出,水解液 COD、SCOD 浓度迅速回升,pH 值迅 速降低,TVFAs 先增加后降低;水解液大出料量更有利于秸秆有机物水解溶出,水解液排空的处理累积 COD 获得量、TS 损失率、半纤维素 损失率和纤维素损失率较排 1/3 的处理分别提高 44.45% 、25.97% 、30.23%和 43.34%,排空的处理单位秸秆水解获得 COD 质量达 0.33g COD/g 秸秆;水解液回流对秸秆有机物水解溶出并未表现出明显的促进作用,但在实验后期对日产气量及产气中甲烷含量影响明显,3d 回流 1 次的处理累积产气量和产气中甲烷含量均高于不回流和 1d 回流 1 次的处理. 关键词：打捆麦秸；水解液；出料量；回流 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2013)11-2006-07 Effect of output and reflux of hydrolysate on hydrolysis and acidification process of agricultural straw. CHEN * Guang-yin, LV Li-li, CHANG Zhi-zhou , YE Xiao-mei, XU Yue-ding, ZHANG Jian-ying (East China Scientific Observing and Experimental Station of Development and Utilization of Rural Renewable Energy, Ministry of Agriculture, Institute of Agricultural Resources and Environment, Jiangsu Academy of Agricultural Sciences, Nanjing 210014, China). China Environmental Science, 2013,33(11)：2006~2012 Abstract ：Effect of output and reflux of hydrolysate on hydrolysis and acidification process of baling wheat straw were investigated by batch model at (37±1)℃. Ejected the hydrolysate from anaerobic system was good for the dissolving of organic matter of wheat straw. After hydrolysate ejection, more organic matter of wheat straw were dissolved into hydrolysate and content of COD and SCOD increased and pH value decreased rapidly while content of TVFAs increased in the initial stage and than decrea