水泥窑PM2.5排放特性及其PAHs风险分析.pdfVIP

中国环境科学 2014,34(5) ：1113~1118 China Environmental Science 水泥窑 PM2.5 排放特性及其 PAHs 风险分析 韦 琳,唐海龙,郭盈盈,邹正禹,刘阳生* (北京大学环境科学与工程学院,北京市固体废弃物资源化技术与管理 重点实验室,北京 100871) 摘要：采用荷电低压颗粒物撞击器(ELPI)、便携式 PM2.5 采样器和稀释系统,对国内 3 家新型干法水泥生产厂(5 条生产线) 的水泥窑(包括 窑头和窑尾)进行现场采样,分析水泥窑排放 PM2.5 的质量浓度、粒数浓度及其中的多环芳烃(PAHs)浓度,对呼吸致癌风险进行评价.结果表 明:从粒数浓度分析,PM2.5 中 70% 以上为 PM0.33,这部分颗粒物主要是由气化凝结形成的.各采样点排放的 PAHs 主要以二环和三环的低环 3 PAHs 为主.第 3 个水泥厂窑头排放的 PAHs 含量最高,而且苯并[a]芘(BaP)超过国家所规定的 8ng/m 标准限值, 同时其呼吸致癌风险 平为 -4,高于可接受致癌风险水平的上限,需要有效处理. 4.46 ×10 关键词：细颗粒物；水泥窑；多环芳烃；致癌风险 中图分类号：X513 文献标识码：A 文章编号：1000-6923(2014)05-1113-06 Characteristics of PM2.5 emitted from cement kiln and the risk assessment of PAHs in PM2.5. WEI Lin, TANG * Hai-long, GUO Ying-ying, ZOU Zheng-yu, LIU Yang-sheng (Beijing Key Laboratory for Solid Waste Utilization and Management, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China). China Environmental Science, 2014,34(5)：1113~1118 Abstract ：An electrical low-pressure imapctor (ELPI) and a portable PM2.5 sampler equipped with an air dilution system were employed to investigate the emission characteristics of PM2.5 from the cement manufacturing process. Three new dry cement manufacturing enterprises located in the northern China were chosen. Mass concentration and particle number concentration of PM2.5 emitted from the outlet of precipitator at the kiln head and the rear were examined, and concentration of PAHs in PM2.5 was also investigated. Afterwards, cancer risk levels resulting from PAHs inhalation were calculated. Experimental results showed