层状化合物K-%2c2-Ln-%2c2-Ti-%2c3-O-%2c10-及其复合物制备和光催化活性研究.pdf

硕士论文 层状化合物K2Ln2Ti30lo及其复合物的制各和光催化活性研究 摘要 层状材料是一种重要的功能材料，由于其特有的层状结构和层间化学反应活性使 其在离子交换、吸附、传导、分离和催化等诸多领域具有广阔的应用前景。 结果。制备K2Ln2Ti30lo的过程中，发现了由中间产物KLn2n3095向目标产物转变的 过程。用微乳液法合成KLn2Ti309 20nmX20nm左右的方块状晶体，具有较大的比表面积，是一类具有层状结构的新化 合物。 研究了改性过程中酸交换、烷基胺预撑、无机粒子柱撑；将AlE03和Ti02为柱 关键词：钙钛矿型层状化合物；稀土；微乳液；柱撑；光催化 as ofit’S fieldssuch andchemicalreaction ininterlayerspace． peculiarlayerdconfiguration activity Layeredperovskite-typecompound characterized were microemulsionobtained were preparedby method，the products by andUV—Vis structuresof XRD，TEM，LAM，FT-IR spectra．Crystal wasfoundthat Was resolved K2Ln2Ti3010 Ce，Pr,Sm，Eu)were byFullprofprocedure．It fromamediate inthe of seriesof state-KLn2Ti309．5 K2Ln2Ti30lo．A changing preparation by compoundsKLn2Ti309．5(Ln=La，Nd，Sm，Dy，Er)wereprepared resultsindicatedthat was andthe sizewasca． method，the KLn2Ti3095 square—likeaverage BETsurfaceareaand structuresimilartotheaim 20nm，hadhigher uniquelayered are obtained anewkind products．The layeredcompounds． products ofperovskite-type The reaction as and interlayer process，suchacid—exchanging，alkylamineinorganic