锂离子电池正极材料镍钴酸锂的研究.pdfVIP

摘要 层状结构的Li-Ni-Co-O化合物 (典型化合式为LiNio,Co-Oz)作为一种替 代LiCoO:的新型铿离子电池正极材料，引起了国内外电池工业界极大关注。它 具有比容量高 (140mAh/g-180mAh/g)、价格相对低廉等优点。作者考察了液相 法和固相法两种制备方法对材料电化学性能的影响，发现固相法是最可行的制 备方法。而且Li源采用LiOH·H10,Ni源采用Ni(OH)z是最可行的制备路线。 作者采用固相法制备的LiNio.eCo-O:可逆比容量最高达158mAh/g，循环到 第50次比容量135mAh/g，表现出较好的电化学性能。但是存在粒度分布过宽， 颗粒尺寸和形态难以控制等不足，而且材料的循环性能仍有待提高。 作者在一年多的实验中发现:镍钻酸铿制备困难苛刻，制备工艺条件的细 微变化就导致材料的电化学性能的显著差别。作者综合大量实验数据和许多文 献以及互连网信息认为制备性能优良的镍钻酸铿的关键在于原料纯度、原料反 应活性、锻烧工艺以及设备。 关键词:铿离子电池 层状结构 Li-Ni-Co-O化合物 Abstract ThelayeredLi-Ni-Co-Ocompound(therepresentativemoleculeis LiNio.-Coo.z02)isbeingconsideredforuseasacathodematerialin lithium-ionbatteriessubstitutetoLiCoO,,thematerialofLiNi,Co,-,0_ hasdrawnmuchattentioninbatteryindustryintheworldbecauseithas highcapacity(l40mAh/g-180mAh/g)andlowercost.Theauthorhastest theelectrochemicalbehaviorofLiNi,Co,_,仇intermofdifferentsynthesis routessuchasliquidreactionandsolid-statereaction,the authorhas foundthatthesolid-statereactionwasthemostfeasiblemethod and LiOH·H,O 、Ni(OH)}werethemostpracticablematerialsourceto synthetizeLiNi.Co,-,02inalllithiumcompoundandnickelcompound. ThematerialofLiNi，NCO.z0_.madebysolid-statereactionhasahigh capacityfor 158mAh/g，itpreserved135mAh/gafter50cyclesandshown comparablegoodelectrochemicalproperty.Unfortunately,theproduct exhibitsignificantwidthofparticledistribution，thediameterand physiqueofparticleweredifficulttocontrol，alsothecycling stabilitywasawaittoimprove. Inoneyearsexperimenttheauthorhasfoundthatthematerialof LiNi,Co,-,Ozwashardtoprepareandminutenessshiftingofprepare conditionleadtosalientdifferenceofproductselectrochemical property.Combingexperiment.literatureandmuchinternetinformation, theauthorconcludethatthekeytoprepareLiNi.Co,一，0,withexcellent performancewerefineness,activeofreagent，theheatingtechnicand theequipment. Keyword:lithium-ionbattery layeredstructure Li-Ni-Co-Ocompound