低温水热合成异形TiO2纳米晶及其表征.pdfVIP

理化学学报(Wuli Huaxue Xuebao) 856 Acta Phys. Chim. Sin., 2007, 23(6) ：856-860 June [Article] 低温水热合成异形TiO 纳米晶及其表征 2 霞1, 赵 岩2 彩碚1 孟 皓1 1 2 ( 东北大学理学院, 沈阳 110004; 中国科学院金属研究所, 沈阳 110016) 摘要： 70 益下在钛酸四丁酯(TBOT)水热合成TiO2 过程中, 加入油酸, 控制TiO2 颗粒的生长方向, 无需热处理, 直接得到针状和纺锤形锐钛矿TiO2 纳米晶. 应用透射电子显微镜、X 射线衍射仪对TiO2 纳米晶进行了形貌观 察和晶体结构的测定. 外光谱分析表明, 油酸分子以静电作用吸附于针状TiO2 纳米晶的表面. 根据UV Vis 吸 收峰, 计算了TiO2 纳米晶的禁带宽度. 纺锤形TiO2 纳米晶具有较高的光催化活性, 60 min 内催化降解了90% 的 罗丹明B. 关键词： TiO2 纳米晶; 针状; 纺锤形; 光催化 中图分类号： O643 Synthesis and Characterization of TiO Nano crystalline with Different 2 Morphologies by Low temperature Hydrothermal Method ZHANG Xia1, ZHAO Yan2 ZHANG Cai Bei1 MENG Hao1 1 ( School of Science, Northeastern University, Shenyang 110004, P. R. China; 2Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, P. R. China) Abstract ： Oleic acid was used in low temperature hydrothermal reaction of tetrabutyl titanate (TBOT) to control the growth direction of TiO particles. TiO nano crystallines in the shapes of needle and spindle were synthesized. The 2 2 morphology and structure of these TiO2 particles were confirmed by means of TEM and XRD. The FT IR spectrum an