长期热致吸放氢循环对载钯硅藻土储氢性能的影响.pdfVIP

25 3 Vol.25 No.1 2 0 1 1 6 CHINESE JOURNAL OF MATERIALS RESEARCH June 2 0 1 1 1,2 1,2 1 1 1 1 1. 110016 2. 100049 PdCl2 – – (Palladium/Kieselguhr, Pd/K), PCT , 1000 2000 , Pd/K PCT , , Pd/K , 1000 2000 (150 µm) 0.21% 3.98% , , , , TG139 1005-3093(2011)03-0327-06 Effect of Long–term Thermal Cycling Absorption Process (TCAP) on Hydrogen Storage Performance of a Palladium/Kieselguhr Composite CHEN Wei1,2 LUO Gang1,2 XIONG Liangyin1 CHEN Demin1∗ LIU Shi1 YANG Ke1 1.Institute of Metal Research, Chinese Academy of Science, Shenyang 110016 2.Graduate School of Chinese Academy of Sciences, Beijing 100049 Manuscript received March 14, 2011; in revised form April 8, 2011. * To whom correspondence should be addressed, Tel:(024 E–mail:demin.chen.l@imr.ac.cn ABSTRACT A palladium–kieselguhr composite (Pd/K) was prepared by the PdCl2 dipping– calcinating–reducing method. Hydrogen storage performances of the Pd/K before and after subjecting to 1000 and 2000 cycles of hydriding–dehydriding test using the TCAP method were investigated, in- cluding phase analysis, morphology observation, pressure–composition isotherm (P − C − T curve) and hydrogen absorption kinetics of the Pd/K composite. Comparing to the initial status, it was found that the absorption rate of the thermally cycled Pd/K greatly enhanced, the P − C − T curve almost retained the same, while the hydrogen uptake capacity decrease