温度对熔体挤出自增强HDPE棒材显微组织和力学性能的影响.pdfVIP

温度对熔体挤出自增强 HDPE 棒材显微组织和力学性能的影响 朱武 黄苏萍 周科朝 李志友 (中南大学粉末冶金国家重点实验室,长沙,410083) 摘要：利用自制模具，在不同的温度下成功的制备了直径为 7.2mm 的自增强高密 度聚乙烯（HDPE）棒材。通过 SEM 观察、DSC 分析、WAXD 分析与力学性能测试， 研究挤出温度对熔体挤出自增强 HDPE 棒材微观结构和力学性能的影响。研究结 果表明，挤出温度是影响熔体挤出自增强 HDPE 棒材结构和力学性能的重要参数。 随着挤出温度的降低，自增强棒材的微晶尺寸和结晶度大幅提高，晶面间距几乎 未变化，熔点向高温区发生漂移，试样内部有大量的微纤结构存在。在 130℃下 挤出棒材的拉伸强度和抗弯强度分别为 220.6Mpa 和 152.9Mpa，都将近是未增强 试样的 10 倍。 关键词：高密度聚乙烯，熔体挤出，自增强，温度，结构与性能 中图分类号：TQ325.1 文献标识码：A The influence of extrusion temperature on microstructure and mechanical properties of self-reinforced HDPE rods ZHU Wu, HUANG Suping, ZHOU Kechao, LI Zhiyou (State Key Laboratory for Powder Metallurgy, Central South University, Changsha, 410083) ABSTRACT: Self-reinforced high density polyethylene (HDPE) rods with diameter 7.2mm were successful prepared at different temperature using homemade mould. Study the influence of temperature on microstructure and mechanical properties of self-reinforced HDPE rods by the SEM observation, WAXD analyses, DSC analyses and tensile strength measurement. The study shows that the extrusive temperature is a very important parameter affecting on the structure and properties of the self-reinforced HDPE rods. With the decreasing of extrusion temperature, crystallite size and crystallinity of self-reinforced rods be promoted significantly, but crystal face distance remain invariability. Melt points drift to high temperature and there exists microfibril in the self-reinforced rods in great bulk. The tensile strength and welding strength of the rods which extruded at 130℃ are 220.6Mpa and 152.9Mpa respectively. They are nearly reached 10 times than those of un-reinforced samples. Keywords: