用于开发高容量电极材料的多电子反应Multi-electronReactions….pdfVIP

7th US-China Electric Vehicle and Battery Technology Workshop, San Francisco, Apr 4-5, 2013 用于开发高容量电极材料的多电子反应 Multi-electron Reactions for Development of High Capacity Electrode Materials 吴川 吴锋 WU Chuan WU Feng 北京理工大学化工与环境学院 School of Chemical Engineering and the Environment Beijing Institute of Technology Beijing 100081, China E-mail: chuanwu@bit.edu.cn 高比能电池的需求 The Demands for High Energy Density Batteries (HEDB) ED ⎯ 质量能量密度(Wh/kg) 或体积能 量密度(Wh/L) n ⎯每摩尔反应物的电子转移数 E0 ⎯反应电动势 ΣM ⎯ 活性物总质量 i ED ⎯ Energy density, either per unit of weight (Wh/kg) or per unit of volume (Wh/L) n ⎯the number of electrons transferred per mole of reactants in a cell reaction E0 ⎯the electromotive force (emf) of the cell reaction ΣMi ⎯the sum of the formula weights of active materials being transformed in the cell reaction (redox drivers) Energy Environ. Sci. 3 (2010) 174–189 高比能电池用高容量电极材料的设计 High Capacity Electrode Materials for HEDB The Faraday’s Law C ⎯ the theoretical capacity of the electrode material F ⎯ the Faraday constant n ⎯ the total electric charge passed through the electrode M the molar mass of the electrode material ⎯ 1摩尔这种硼化物在特定电化学反应中能够转移的电子数大于1摩尔，因而被视 为多电子材料，并具有实现超高比容量的潜力。 “……one mole of such borides can transfer more than one mole of electrons through specific electrochemical reactions, such that they can be r