热解升温速率对有机质生烃动力学参数影响.pdfVIP

Advances in Geosciences 地球科学前沿, 2013, 3, 1-7 doi:10.12677/ag.2013.31001 Published Online February 2013 (/journal/ag.html) Influence of Heating Rates on Kinetic Parameters of * Hydrocarbon Generation from Organic Matter 1,2 1 2 1 1 1 Min Wang , Yefeng Sun , Shuangfang Lu , Guohui Chen , Qi Dong , Xuefei Wang , 1 1 1 Xintong Yan , Yang Li , Wenguang Wang 1Earth Sciences Institute, Northeast Petroleum University, Daqing 2China University of Petroleum (Huadong), Research Institute of Unconventional Petroleum and Renewable of Energy, Qingdao Email: quickking@163.com Received: Dec. 11th th nd , 2012; revised: Dec. 27 , 2012; accepted: Jan. 2 , 2013 Abstract: Open system pyrolysis experiments with multiple heating rates (10˚C/min, 20˚C/min, 30˚C/min, 40˚C/min, 50˚C/min) of different types of organic matter samples have been accomplished. The kinetic model parameters can be calibrated by using the experimental data of different heating rates (10˚C/min-20˚C/min-30˚C/min, 20˚C/min-30˚C/min- 40˚C/min, 30˚C/min-40˚C/min-50˚C/min). Results show that the hydrocarbon processes of different types of organic matter can all be described by the parallel first-order rate model. Therein, the activation energy distribution range of type I organic matter is relatively narrow, distributed mainly in the major part of the activation energy. The activation energy distribution range of type III organic