材料加工形态学2-2.加工形态性能 实例.pptVIP

注塑成型中利用应力场（剪切）控制聚合物形态——剪切控制取向注塑(SCORIM) 注塑过程利用应力场（剪切）对聚合物形态控制研究进展——剪切控制取向注塑(SCORIM) * * * * * Multilayer morphology Selective permeable morphology Interpenetrating (sponge) morphology Fibrous morphologies Conducting networks Applications of chaotic mixing in morphology manipulation Zumbrunnen DA et al. Nano Lett. 2002; 2(10): 1143 Multilayer morphology Selective permeable morphology Zumbrunnen DA. Polymer 2002; 43(11): 326 Interpenetrating morphology Liu YH, Polym. Compos. 1996; 17: 187 Fibrous morphologies Danescu RI, J. Vinyl Addit. Technol. 2000; 6: 27 Conducting networks Influences of tailored morphology on the properties Conducting networks Multilayer morphology Schematic of SCORIM Shen, et al. Bevis, et al. SCORIM对凝聚态和相形态的影响 Chain orientation Crystal structure Phase morphology for multi-phase polymers Mechanical properties Other properties, e.g. optical, barrier, etc. Surface appearance of the parts Subskin Dynamic molding Core Immediate Conventional molding 动态剪切场对分子链取向的影响 Skin-Core Dynamic Shear injection molding HDPE Shish-kebab iPP Interlocking shish-kebab HDPE(5000S)的拉伸强度可从23.0MPa提高到93.0MPa，提高300％。iPP的拉伸强度在纵横方向上从32MPa提高到63MPa (a) (b) AFM images for PP/LLDPE(50:50), a: co-continuous structure; b: sea-island structure。Q Fu, et al. Macromol Rapid Comm, 2003 多相聚合物 SEM for PC/PE blend (10/90) SN Li, ZM Li, et al. Polymer, 2006, 47:4497 Scattering patterns of 2d-SAXS photography of HDPE/iPP(20/80) blends In HDPE phase In iPP phase Flow direction HDPE在iPP晶面上发生外延附生结晶 Q Fu, et al. Polymer, 2005 2D WAXS patterns 普通注塑 iPP纯样 动态注塑 iPP纯样 普通注塑 PET/iPP 维纤化共混物 动态注塑 PET/iPP 维纤化共混物 SCORIM和原位微纤网络对制品皮芯结构的抑制 a’:普通注塑 iPP纯样; b’:动态注塑 iPP纯样; c’: 普通注塑 PET/iPP 维纤化共混物; d’: 动态注塑 PET/iPP 维纤化共混物 *