聚合物受限结晶研究进展.pdfVIP

V ol. 2 1 N o. 4 452 Journal of Functional P olymers 2008 12 张凤波, 于佩潜, 谢续明 ( 清华大学化学工程系, 高分子研究所先进材料教育部重 实验室, 北京 100084 : 随着纳米材料研究的迅速发展, 聚合物由于其分子固有的纳米尺度结构, 无论作为纳米 器件或在模板应用方面都受到广泛瞩目在微纳领域的应用中, 特定受限环境下, 结晶聚合物的结 晶行为也因此受到广泛关注本文从均聚物( 及无规共聚物 和半晶型嵌段聚合物两方面总结了近 年来聚合物受限结晶领域的研究进展对于均聚物和无规共聚物, 人们主要关注其在薄膜超薄膜 条件下的受限结晶性能, 关注 为随着膜厚减小而引入的空间效应和界面效应对聚合物结晶性能 的影响而对于半晶型嵌段共聚物受限结晶的研究则多从本体出发, 来研究纳米相分离与结晶的 竞争过程纳米相分离区域对于可结晶嵌段结晶生长的几何限制( 空间效应 以及嵌段连接 ( 结晶 嵌段的末端 对于结晶嵌段结晶行为的影响 : 受限结晶; 聚合物薄膜; 半晶型嵌段聚合物 : O63 : A : 2008 Studies on Confined Crystallization of Polymers Z H A N G Fengbo, Y U Peiqian , XIE X uming ( St at e Key Laborat ory of A dvanced M at erials , Inst it ue o f Poly mer Science and Eng ineer ing, Depart ment of Chem ical Engineering, T sing hua U niversit y, Beijing 100084, China Abstract: Now aday s, great at tent io n has been paid t o co nf ined crystallizat ion o f polym ers under specific environment due t o t heir w ide applicatio ns in t he f ield of nano mat er ials , such as m iniat urized com po nents and nanopat t erned t em plat es . T he prog ress in the st udy on co nf ined cryst alliz ation of poly mers is review ed in t his paper . Fo r t hin and ult rathin f ilms o f homopoly mers and random co po lymers, the conf ined crystallizat ion is w idely studied on t he basis of g eo metr y ef fect and int erfacial ef f ect, w hich beco me dominant w hile t he f ilm t hickness is reduced . A s f or block copolym er s, w it h unique nano phase separat ion st ruct ure, t he confined cryst alliz at ion in t he bulk is due t o the compet it ion bet w een vit rificat ion of amor phou s blo ck and cry st alliz