aCl2-H2O和MgCl2-H2O体系流体包裹体分析中的应用Ⅰ低温拉曼光谱研究 Application of in situ cryogenic Raman spectroscopy to analyze synthetic fluid inclusions in the systems CaCl2-H2O and MgCl2-H2O Ⅰ Cryogenic Raman spectra.pdfVIP
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10000569/2008/024(09)196167 ActaPetrologicaSinica 岩石学报
原位低温拉曼光谱技术在人工合成 CaClH O和
2 2
MgClH O体系流体包裹体分析中的应用 :
Ⅰ
2 2
低温拉曼光谱研究
1,2 1 2 1
丁俊英 倪培 JeanDUBESSY 张婷
1,2 1 2 1
DINGJunYing ,NIPei ,JeanDUBESSY andZHANGTing
1.南京大学内生金属矿床成矿机制研究国家重点实验室,地质流体研究所,地球科学与工程学院,南京 210093
1.StateKeyLaboratoryforMineralDepositResearch,InstituteofGeoFluid,SchoolofEarthScienceandEngineering,NanjingUniversity,
Nanjing210093,China
2.G2R,CNRS,NancyUniversité,BP23954506VandoeuvrelèsNancy,France
20080510收稿,20080731改回.
DingJY,NiP,DubessyJandZhangT.2008.ApplicationofinsitucryogenicRamanspectroscopytoanalyzesyntheticfluid
inclusionsinthesystemsCaClHO andMgClHO I:CryogenicRamanspectra.ActaPetrologicaSinica,24(9):
2 2 2 2
1961-1967
Abstract InsitucryogenicRamanspectroscopywasappliedtotheanalysisofsyntheticfluidinclusionsinthesystemsCaClHO
2 2
andMgClHOwhichwereformedatexperimentalconditions.Itisshownthatthesalthydrates(CaCl·6HOandMgCl·12HO)
2 2 2 2 2 2
ofCaClandMgClformedinaqueoussolutionsinlowertemperaturehavethespecificRamanspectrarespectivelyandcanbeusedas
2 2
2+ 2+
thestandardtoverifytheexistenceofthebivalentcationsCa andMg whicharecommonlypresentinthefluidinclusionsofthe
HOsaltsystemsandcanreflectthecompositionoffluidinclusions.ThisstudyshowthatinsitucryogenicRamanspectroscopyisthe
2
effectivecomplementoftheconventionalmicrothermometryanditwillbeusedmoreandmorewidelyinfuturefluidinclusionresearch
field.
Keywords Syntheticfluidinclusion;Cryo
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