加热条件对炭泡沫材料孔结构和性能的影响.pdfVIP

第 24卷 第 4期 新 型 炭 材 料 Vo1．24 No．4 2009年 12月 NEW CARB0N MATERIALS Dec．2009 ArticleID： 1007—8827(2009)04-0321-06 Effectofheatingconditionson porestructure and performanceofcarbonfoams W ANG Yong—gang， M IN Zhen—hua， CAO M in， XU De—ping (SchoolofChemicalandEnvironmentalEngineering，ChinaUniversityofMiningandTechnology，Belting 100083，China) Abstract： Carbonfoamswerepreparedfrom ARpitchinahighpressure／hightemperaturereactorunderdifferenthea— tingconditions．Theirporestructure，bulkdensity，porosity，compressivestrength，thermalconductivity，andcrystallite sizeparametersweremeasured．Foam sproducedusingalongtimeataconstantfoaming temperatureexhibitbiggerpore size(412am)，higherporosity (83．82％)，lowerbulk density (0．34g／cm )，highercompressives~ength (4．92MPa)．andmoreinterconnectedporesthanthatproducedinashorttimeatthesameconstantfoma ingtempera— ture，whichexhibithighthermalconductivity(71．34W／(m ·K))andlow interlayerd-spacing(d )(0．33556rim) after graphitization at 2800 ℃． The specific thermal conductivity of graphite foams can reach 210(W ·(m ·K) )／(g·cm )，whichisaboutfivetimesgreaterthancoppernadfourtimesgreaterthna aluminum． Keywords： Carbonfoma ；Temperaturecondition；Porestructure；Performnace CLCnumber： T0 127．1 1 Documentcode： A 1 Introduction ThepropertiesOfAR pitcharelisted inTable 1．The system was pressurized ofr2．0MPa．4．0MPa．or Since firstappeared in 1997 ．carbon ofam 6．0MPabyN，．whenitwasheatedtosofteningpoint withhigh thermalconductivity have becomepopular ataconstantheating rate．then heating to finaltern— int