谷壳对水中镉离子的吸附动力学及热力学研究.pdfVIP

安徽农业科学,Journal of Anhui Agri . Sci .2009 ,37(7) :3190 - 3192 责任编辑 金琼琼 责任校对 卢瑶 谷壳对水中镉离子的吸附动力学及热力学研究 陈云嫩, 丁元春 ( 江西理工大学资源与环境工程学院, 江西赣州341000) 摘要 [ 目的] 研 究谷壳吸附水 中镉 离子的吸附过程及其影响因素。[ 方法] 以间歇吸附的方式考察 了溶液pH 值 、反应时间、反应温度、 镉 离子初始浓度等物化参数对吸附过程 的影响, 并对吸附过程进行动力 学与热力 学研 究。[ 结果] 吸附过程符合 Langmuir 吸附等温模 式。谷壳对镉 离子的吸附动力学模型较好地符合 了准二级动力学方程 。当反应温度为298 K,pH 值为6 , 谷壳投加量为4 g/ L , 振 荡速度 为150 r/ min , 反应时间为30 min 时, 谷壳对镉 离子的吸附效果最好 。随着反应温度的升高, 谷壳对镉 离子的吸附加快。该吸附反应 的焓 变值为正, 自由能变值为 负。[ 结论] 谷壳是处理镉废水的有效的低成本吸附剂, 其吸附过程是 自发的吸热反应 。 关键词 吸附; 谷壳; 镉; 动力学; 热力学 中图分类号 X703 文献标识码 A 文章编号 0517 - 6611( 2009) 07 - 03190 - 03 Kinetics and Thermodynamics Study on the Adsorption of Husk to CadmiumIons in Water CHEN Yun-nen et al ( College of Resource and Environmental Engineering ,Jiangxi University of Science and Technology ,Ganzhou ,Jiangxi 341000) Abstract [ Obj ective] The purpose was to study the adsorption process of husk to cadmi umions i n water and its i nfluencing factors .[ Method] The influ- ences of physical and chemical parameters such as pHvalue ,reaction ti me and temperature and the initial concn .of cadmiumions on the adsorption process were investigated by batch adsorption .And then the adsorption process was studied in kinetics and thermodynamics .[ Result] The adsorption process ac- corded with Langmuir adsorption isother mal model .The dynamic adsorption model of husk to cadmi umions accorded with quasi-second dynamic equation better . When the reaction temperature was 298 K,pHvalue was 6 ,husk addition was 4 g/ L,shaking velocity was 150 rpmand reaction ti me was 30 min , the adsorption effect of husk on cadmi umions was best .As the reaction temperature increased ,the adsorption of husk to cadmiumions was accelerated .The enthalpy change of the adsorption was positive and its free energy ch