硅-硅氧化物-锡-碳复合物论文：锂离子电池负极材料硅—硅氧化物—锡-碳的制备及性能研究.docVIP

硅-硅氧化物-锡/碳复合物论文：锂离子电池负极材料硅—硅氧化物—锡/碳的制备及性能研究 【中文摘要】碳材料作为锂离子电池负极材料,具有很好的循环寿命和安全性。尽管碳材料表现出良好的可逆性和循环性,但理论比容量只有372 mAh g-1,无法满足高能量密度的电子产品和电动车用锂离子电池的需要。作为锂离子电池负极材料硅具有最高的理论比容量(4200 mAhg-1),锡也具有较高的理论比容量(994 mAhg-1).但是,在电池充放电过程中,随着锂离子的嵌入和脱出,其体积膨胀和收缩很大而很容易碎裂,导致电极被破坏而在几个循环后容量衰减很快,甚至消失。因此,目前大量的研究工作者都致力于研究和解决其循环性能差的问题。本论文根据大量的国内外文献资料调研,紧跟该领域的研究前沿,采用碳热 【英文摘要】Carbon materials are utilized as anode materials for the improvement of safety and cycle life in lithium batteries. Although carbon materials show good reversibility and stability for cycles, their specific capacities are limited to 372 mAh g-1.It can抰 satisfied the demands of high-energy-density lithium batteries in electronics and electrical vehicles.As anode materials for Li-on batteries, silicon has a highest theoretical specific capacity of 4200 mAh g-1, tin has aspecific capacity of 994 mAh g-1. But silicon and tin undergo large volumetric change during lithium insertion, it is regarded that the expansion and contraction of lithium silicide during the charge-discharge cycling leads to the pulverizing of Si and Sn powder is formed.It would cause the breakdown of the electrode materials, resulting in the loss of capacity within several cycles. Therefore, many research works were carried out on methods to study and improve its cycle life in recent years.This dissertation is a result of research work in the area of Li-ion batteries, and it is believed that the subject under study is a frontier of current research topics. The modified Si-SiOx-Sn/C has been synthesized by a carbon thermal reduction method and a high temperature solid-state method, the influence of various temperatures and modify were investigated in this work through a series of experiments, and following conclusions were drawn:1. Si-SiOx-Sn/C composites were prepared by a carbon thermal reduction method. The electrochemical performance of the composites as anode material for lithium-ion batteries was studied.The composites were prepared at different tempera