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Electrochemical studies for the electroactivity of amine-capped aniline教程.pdf

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European Polymer Journal 45 (2009) 485–493 Contents lists available at ScienceDirect European Polymer Journal journal homepage: www.elsevi /locate/europolj Electrochemical studies for the electroactivity of amine-capped aniline trimer on the anticorrosion effect of as-prepared polyimide coatings Kuan-Yeh Huang a, Yu-Sian Jhuo a, Pei-Shan Wu a, Chieh-Hisen Lin a, Yuan-Hsiang Yu b, Jui-Ming Yeh a,* a Department of Chemistry and Center for Nanotechnology at CYCU, Chung-Yuan Christian University, No. 200, Chung-Pei Road, Chung Li 32023, Taiwan, ROC b Department of Electronic Engineering, Lan-Yan Institute of Technology, I-Lan 261, Taiwan, ROC a r t i c l e i n f o a b s t r a c t Article history: The electroactive polyimide consisting of various content of amine-capped aniline trimers Received 12 March 2008 (ATs) have been successfully synthesized and characterized by Fourier-Transformation Received in revised form 21 October 2008 infrared and UV–visible absorption spectroscopy. The electroactivity of as-prepared polyi- Accepted 24 October 2008 mides was tested by electrochemical cyclic voltammetry (CV) studies. It was noticed that Available online 5 November 2008 the as-prepared electroactive polyimide with higher content of amine-capped ATs shows higher electroactivity (i.e., larger redox current) than that of non-electroactive polyimide, leading to enhance corrosion protection efﬁciency on cold-rolled steel (CRS) electrodes