基于FTIR分析的稻草热解机理_英文_.pdfVIP

PRODUCT ENGINEERING AND CHEMICAL TECHNOLOGY Chinese Journal of Chemical Engineering, 17(3) 522—529 (2009) Mechanism Study of Rice Straw Pyrolysis by Fourier Transform * Infrared Technique FU Peng (付鹏), HU Song (胡松)**, XIANG Jun ( 向军), SUN Lushi (孙路石), YANG Tao (杨涛), ZHANG Anchao (张安超) and ZHANG Junying (张军营) State Key Lab of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China Abstract The pyrolysis mechanism of rice straw (RS) was investigated using a tube reactor with Fourier trans- form infrared (FTIR) spectroscopy and thermogravimetric analyzer. The results show that the maximum pyrolysis rate increases with increasing heating rate and the corresponding temperature also increases. The three-pseudocomponent model could describe the pyrolysis behavior of rice straw accurately. The main pyrolysis gas products are H O, CO , CO, CH , HCHO (formaldehyde), HCOOH (formic acid), CH OH (methanol), C H OH 2 2 4 3 6 5 (phenol), etc. The releasing of H O, CO , CO and CH mainly focuses at 220-400°C. The H O formation process is 2 2 4 2 separated into two stages corresponding to the evaporation of free water and the formation of primary volatiles. The release of CO first increases with increasing temperature and gets the maximum at 309°C. The releasing behavior 2 of CO is similar to H O and CO between 200 and 400°C. The production of CH happens, compared to CO and 2 2