等离子体协同MnO_x_SBA_15催化氧化正己醛影响因素研究.pdfVIP

第5卷 第5期 2010 年 5 月 中国科技论文在线 SCIENCEPAPER ONLINE 355 等离子体协同 MnO /SBA-15 催化氧化正己醛 x 影响因素研究 向 东，赵国涛，叶代启 （华南理工大学环境科学与工程学院，广州 510006 ） 摘 要：采用浸渍法制备了MnO /SBA-15 催化剂，利用BET和XRD对催化剂进行表征。考察了各影响因素对介质阻 x 挡放电等离子体协同MnO /SBA-15 催化剂对降解正己醛的影响。结果显示，负载MnO 后的SBA-15 仍然保持介孔结构； x x 等离子体与催化剂表现出较好的协同作用，干燥气氛下MnO 负载量为10%时降解效果较好，正己醛去除率达99% ； x 相比干燥气氛，相对湿度低于20%可提高正己醛去除率，但高于20% 时催化效果下降；正己醛去除率随初始浓度或气 体流量的增加而下降。 关键词：餐饮油烟；VOC ；正己醛；介孔分子筛；低温等离子体 中图分类号：X51 文献标识码：A 文章编号：1673 －7180(2010)05 －0355 －5 Study on factors influencing Hexanal oxidation by plasma-assisted MnO /SBA-15 catalysis x Xiang Dong，Zhao Guotao，Ye Daiqi (College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China) Abstract: MnOx supported mesoporous molecular sieves SBA-15 were prepared by impregnation method, and characterized by BET and XRD. The factors influencing Plasma-assisted catalysis oxidation of hexanal over MnOx/SBA-15 catalysts was investigated with dielectric barrier discharge (DBD) reactor. Results showed that the mesoporous structure of the SBA-15 was retained after MnOx loading. Good synergetic efficient appeared between the catalyst and plasma, with the highest hexanal removal efficiency of 99% at MnOx loading of 10% and voltage of 7.5 kV. Relative humidity below 20% promoted the oxidation of hexanal. However, higher relative humidity reduced the catalytic property. In addition, removal efficiency