关于光二聚合成环丁烷四羧酸二酐（CBDA）反应产率探究-毕业论文.docVIP

关于光二聚合成环丁烷四羧酸二酐（CBDA）反应产率的探究 摘 要 论文在压汞灯的紫外光照射条件下，以顺丁烯二酸酐和乙酸乙酯为原料发生光二聚反应合成了环丁烷四羧酸二酐（CBDA）。首先，我们以紫外全透过二氧化硅玻璃作为冷阱，以1000ml大圆底烧瓶作为反应容器，以从小到大6种不同浓度的反应物作为原料进行对比，在各浓度条件下分别反应4h，实验结果表明：在固液比15.8-4.2浓度范围内，浓度越小，产率越高；然后，我们在上述各浓度下，反应6h，实验结果表明：反应物反应时间越长，产率越大；接下来我们选取了型号相同的新旧程度不同的两个汞灯作为对比，实验结果表明：新压汞灯能生成更多的目标产物环丁烷四羧酸二酐。然后，我们换取550ml小瓶，分别在所选取的浓度为15.8,7.8,5.4的条件下反应6h，8h，实验结果再次证实：在一定范围内，反应时间越长，CBDA的产率越高；同时新灯的产率和绝对产量均高于旧灯。最后，我们选取小圆底烧瓶，并在新灯和旧灯产率最高的一组的浓度下进行光照8h,并循环光照3次，实验结果表明：连续光照可以大幅度提高反应的产量和产率。 关键词:顺丁烯二酸酐；环丁烷四羧酸二酐；压汞灯紫外光照；产率 ABSTRACT ABSTRACT：窗体顶端 In this paper, under the condition of pressure mercury, the maleic anhydride and the ethyl acetate, as raw material, synthesize cyclobutane tetradianhydride (CBDA). We take the dioxide silica glass as the cold pitfall, the 1000ml flask as the reaction vessel, contrast 6 kind of different densitys reactants. Firstly, we chose 4 hours as reaction time separately under various densities condition, the experimental result indicated: when the proportion of liquid-solid is in 15.8~4.2 scopes, the density is smaller, the production rate is higher; Then, under above various concentrations, we chose respond 6h, the experimental result indicated: The reactant reaction time is longer, the yield is bigger; Then we selected two mercury lamps, the same model but different manufacturers, to take the contrast. the experimental result indicated: The new middle pressure mercury lamp can produce the more goal product. Then, we chose 550ml small flask to contrast, under the condition of 15.8, 7.8 and 5.4 proportion and 6h and 8h, separately, the experimental result confirmed once more: In a certain scope, the reaction time is longer, the CBDA yield is higher; Simultaneously, yield of new lamp is higher than the old lamp. Finally, we selected 550ml flask, reaction time of 8h in the proportion of new lamp and old lamp with highest yield, and circulated reaction 3 times, the experimental result indicated: The continual illumination can enhance the output and yield.