铁基逆水煤气变换催化剂的制备和性能研究.pdf

Abstract Recycle of CO2 is urgent because of its emission threaten environment fearfully. Reverse Water Gas Shift Reaction(RWGS) is one of the most important approach in the reusing of CO . Co-precipitation was used to prepare iron manganeses mixed oxides for 2 the RWGS. The catalysts samples were studied by Micro-reactor ，XRD ，TPR，BET and TEM. The emphasis is to optimize composite and structure of the catalysts with robust activity and thermostability. The activity of catalyst prepared by Fe2+ and Fe3+ starting materials is superior to that of catalyst prepared by individual Fe2+ or Fe3+. Manganese dopant into the iron oxides enhances its activity and thermostability. Fe/Mn based catalyst present higher activity and thermostability than that of Cu/Mn 、Zn/Mn based catalyst.. The optimization composition is Fe2+/Fe3+/Mn=42:16:42. Additives rare earths can further improve activity and thermostability no matter Fe or Fe/Mn catalysts. Co adulterant of CeO and La O can promote the activity and 2 2 3 thermostability of manganeses mixed oxides for the reverse water gas shift reaction. Key Words: Reverse-Water-Gas-Shift reaction；Catalyst；Fe/Mn based catalyst; Rare Earths. 目 录 第一章 文献综述 ………………………………………………………………………1 1.1 引言………………………………………………………………………………1 1.2 逆水煤气变换反应热力学分析…………………………………………………2 1.3 逆水煤气变换反应催化剂的研究进展…………………………………………2 1.3.1 水煤气变换反应催化剂……………………………………………………3 1.3.2 逆水煤气变换反应催化剂…………………………………………………3 1.4 稀土基变换催化剂………………………………………………………………7 1.5 选题依据及研究的内容…………………………………………………………9 1.5.1 选题的依据…………………………………………………………………9 1.5.2 研究的内容